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FAQs on Calcium, Supplements involving Calcium 6
Related Articles: Calcium, Understanding
Calcium & Alkalinity, Live Sand,
Marine Substrates, Reef
Systems, Refugiums,
Related FAQs: Calcium, FAQs 1, Calcium
FAQs 2, Calcium FAQs 3, Calcium
FAQs 4, Calcium FAQs 5,
Calcium FAQs 7. & FAQs on Calcium:
Rationale/Use,
Calcium Measuring/Test Kits,
Sources of Calcium, Calcium Supplements,
Dosing,
Chemical/Physical Interactions, Troubleshooting/Fixing,
& Calcium Reactors,
& FAQs on Calcium Reactors: Rationale/Use,
Selection, Installation,
Operation, Media,
Measuring, Trouble-Shooting,
By Makes/Models, & Calcium
and Alkalinity, Kalkwasser
& FAQs on: The
Science of Calcium & Alkalinity, Importance,
Measure, Sources,
Use of Additives, Troubleshooting/Fixing,
Products,
And where would urchins be w/o
something to grind their Aristotle's Lantern against? Hmmm?
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New Setups And Calcium - 07/27/05
Having read pages of your dialogue with other reefers, before I ask you
anything, I have to thank you for all the stimulating advice/discussion.
<<We're happy to help...>>
I just completed a wooden stand designed to support a 55 gallon tank over a 75
gallon tank. Over the next month I will set up a refugium in the 55 to gravity
feed the 75 main display (80 lbs. of rock) and filter the entire arrangement
with a small 20 gallon sump (approximately 24") under the 75.
<<Great!...love the fact you're adding a large (respectively) 'fuge. Would like
to see a larger sump (you'll eventually wish you had the extra space...for media
reactors, etc.), but I'm glad you're not doing it the other way around.>>
My original plan was to install a plenum and DSB (6") in the fuge using the
method prescribed on your website, and a DSB (5") in the main display with sugar
sized aragonite sand. I am aware of the benefits that can accompany good water
circulation, bugs, and detritivore kits in conjunction with a DSB. However, this
will be my 1st tank.
<<So glad to see you're doing some research.>>
I have a few questions. First, is this too much DSB?
<<Not in my opinion.>>
Second, is there anything that I can do while setting up the plenum and DSB in
the 'Fuge that might induce the release of more calcium into the system from the
aragonite in the substrate?
<<Other than not rinsing the "fines" (these will dissolve more readily) from the
sand, no.>>
Or is there any other substance that I could scatter in the DSB substrate that
might be naturally dissolved by the normally occurring gasses/processes in the
DSB resulting in the release of more calcium?
<<The aragonite sand is already your best option. Why all this concern with
calcium at this stage? Your tank will have plenty of calcium from the salt
mix/aragonite in the system during the cycle period.>>
Third, what method of dosing calcium would you recommend for a beginner with
this kind of system?
<<Frequent partial water changes...really! Until the tank is stocked and you
have an idea (through testing) of the demand on your system for calcium, etc.,
frequent partial water changes will supply what you need. If your testing
determines you need to supplement calcium, the two-part additives work well for
small dosages (gets expensive otherwise), else you might consider Kalkwasser or
adding a calcium reactor.>>
Thanks again.
<<Regards, Eric R.>>
Sky high calcium problems? 7/7/05
Hi,
I read the FAQ about high calcium but didn't see anyone with as high as I
have. I bought a 40 gal setup from a friend with coral and fish etc. Brought it
home, put coral in a diff aquarium I've had setup for years and fish into
quarantine tank. Since the aquarium had been dry for a few hours while in
transport I filled with salt water for the inevitable die off, with all living
things that i could take out) left out. Then gave that a week, drained it then
refilled, and then tested water after another few days of settling. The calcium
was measured at 1275mg/l !!!!!! I didn't trust the test so i went and bought 2
diff types of ca tests, they told the same measurement! How is that even
possible? < I'm not sure. But if it is possible it is almost certainly
toxic. I'd doubt those readings. Are you sure? Okay I know you are sure lets
just fix it. > (two tests used liquid, the other used liquid/powder combo) I
didn't add anything but salt water to the aquarium. < Magnesium is often that
high, but not Calcium. > I think my friend majorly overdosed calcium or
something and it must be precipitated out into the sand and coming back into the
water...other parameters are nitrates 0, ammonia 0, nitrite 0, pH 8.6, Alk
low-normal. Should I continue to do full 40 gallon water changes until it is
better? < Well one 80% or 90% water change should fix it overnight. > or is
there someway of lowering the Ca concentration? < Replacing water is the only
thing to do. If there is some sort of powdered calcium in the substrate (which
is hard to believe) than the entire sand needs to be rinsed clean. > I'm afraid
of even putting anything living into this tank until the Ca levels are much
lower. < I agree. I would also test alkalinity as that is more important than
calcium and may lead to ideas regarding this situation. > I'm assuming levels
that high would harm anything alive? Please offer any advice you can.
Thank you for your time, < Change that water and rinse whatever it is that is
adding that calcium. >
Amy
< Blundell >
-
Calcium/Alkalinity Replacement in Top Off Water -
Hi WWM Crew
Great site, the source of all my aqua knowledge, thanks. I have experimented
with the various options of dosing calcium - two part calcium/buffer and
Kalkwasser. The results seem fine, however I have not tried a calcium reactor
due to limited space and funds. My question is - would it be feasible to run CO2
through a air stone in a 60 litre plastic container (in the garage) of suitable
freshwater with a substrate of either coral sand or aragonite. <Hmm... I'd say
probably better to build a Kalkwasser reactor this way. Calcium reactors are
typically used with water fed from the tank. They run continuously so it's not
really practical to feed constantly with freshwater.>
My theory being the low ph (due to CO2) would dissolve Ca into the water (as
does a Ca reactor). <Well... another item of issue here would be recirculation
within the container. If you're set on a calcium reactor, there are many plans
on the web for building one from PVC... have seen many designs build for less
than $50 in parts. Calcium reactors are actually pretty simple, and you sound
motivated enough to build one. Would check on Ozreef.org first.> The result
would be calcium rich water ready to be used for top off. The Ph can easily be
raised by normal aeration before going into main tank. <Normal aeration will
raise the pH only so much - the action behind calcium reactors creates carbonic
acid - driving off excess CO2 will only do a modicum of good.>
Would this be good practice or is it to easy to be any good. <Consider your
options.>
thanks
Greg
<Cheers, J -- > Tropic Marin Bio-Calcium
Just a quick question if I may. I haven't discovered much discussion on this site or otherwise on the product "Tropic Marin Bio-Calcium." Have
any of you folks used this product and what is your take on it?
<A very fine product from an exemplary company>
I have a 20 gallon and I'm looking for a decent product to maintain/increase calcium without the least amount of headache (e.g.,
Kalk would seem to be a far more labor intensive undertaking). From what little I've read, the Bio-Calcium seems like an easy solution. You
simply sprinkle it into the tank as directed/needed.
<Mmm, better to sprinkle it into make-up water... Not directly into an up and going system>
Naturally, you'd need a buffer for use as necessary. The only negative I've picked up
with respect to the Bio-Calcium is that it tends to increase a tanks salinity over time. Not a big negative, just one to be aware of.
<This is not a practical matter... folks will hopefully be doing enough water changing...>
In sum, if the above doesn't sound like a good direction to go, what calcium/buffer combo could you suggest for a small tank such as mine.
Any particular brand/line? Thanks, I appreciate your observations in advance.
Jon,
Tulsa, OK
<Our various input on this issue is posted, archived on WWM... Bob Fenner>
Calcium
Good morning crew. Real quick question. I couldn't find a specific answer to my question on the site, but I did learn an awful lot about
calcium/alkalinity relationships in the process. I currently supplement the B-Ionic two part solution. However, I wanted to jump start my coralline
growth and read that Seachem's Reef Advantage (dry form) was excellent in doing just that. My question, if I wanted to use the Seachem's for a while,
would I need to stop using the ESV calcium component, or use less in combination with Seachem's?
Always learning,
Eric
<Utilize your test kits here... dose with the SeaChem product, but check to see that your balance of alkalinity/calcium is not drifting too much. Bob Fenner> Understanding Calcium... really understanding it 5/17/05
Hey Anthony,
<howdy!>
Ok, so from my understanding the slurry method is only used to replace daily calcium use.
<Hmmm... to be clear here: every(!) calcium supplement should only be used to maintain a safe average calcium level in the system.>
Which method would you use to raise calcium levels to the desired levels of 350-450ppm if I'm thinking of adding hard corals in
the near future? Nilesh
<I fear you are missing the point overall my friend. Do read here:
http://www.wetwebmedia.com/calcalkmar.htm
and explore the links atop the page(s). Best of luck! Anthony>
Dosing Ca
HI
Do you recommend using Reef Builder or Reef Carbonate along with the Reef Advantage? Or will the excess carbonate throw off my other parameters like
pH and ALK?
<You may not have to add anything else. Just check your dKH and try to maintain between 8-12dkh. I would use Reef Builder if needed. James (Salty Dog)> Calcium
Hello,
<Hello Saurav>
Thanks for all your help you guys are great.
<You're welcome>
I wrote you guys before because I was having problems with high ALK and high Ca. I changed from
Oceanic to Instant Ocean salt and with water changes the level reduced. I am interested now in getting SPS corals. I think I have to start dosing Ca, my number at 420 will reduce I think with more water changes as it has. By the way my ALK is 3.5 meq/L and pH is 8.4. Do you recommend I
start dosing Ca?
<I would maintain 400ppm>
If so what do you recommend to dose with. I have a 55 gallon tank and
Kalkwasser seems to be meant for larger tanks and Ca reactors are pricey. What do you think of Kent Marine Liquid Ca? If you do not think I should start dosing now at what Ca level will it be appropriate time to start dosing?
<As above>
Also will SPS corals, as far as lighting goes, will do ok in my tank particularly
Acropora and Montipora? I have 265 Watts of power compact lighting. Thanks again!
<Personally I like SeaChem's Reef Advantage (dry form). It also includes magnesium and strontium, two important elements. It does not have a caustic ph like
Kalkwasser and will not deplete alkalinity. As far as keeping monti's and
Acroporas or flower pot corals, your lighting would be a bit on borderline, most other corals you could keep. James (Salty Dog)> Fish Stores in San Francisco
Hi,
<Hello there>
It sounds like you guys are from the bay area. I live in San Francisco. I get
most of my livestock and supplies from 6th Ave aquarium but am starting to feel
skeptical. Their prices are great but some of their advice resulted in minor
catastrophe. What are your favorite stores in the bay area?
<Will have to ask Chuck Rambo re... or Sabrina... or Paul Mansur... they are all
from the general area, not me>
I have a SERIOUS problem with Calcium (level is at 720, pH is at 8.0 but I see
no precip when adding buffer). I just read that Oceanic salt can cause this so I
am off to Nippon to get some water. They use sea water and I have a 12-gal tank.
Do you think this is wise? Thanks a bunch!
<... something is off here... first, I would "check the checker"... this test
kit/device is likely off... I would be very careful with such a tiny system in
terms of matching well-seasoned, pre-mixed water of similar quality...>
Annie
San Francisco
<Bob Fenner> Calcium problems
Hello crew,
Researching your site has been somewhat of a help, but with my problem there has been no real
answer. My tank is four months old and my problem lies with keeping my calcium at or above 350ppm. I
have recently been dosing Kalk slowly at night for various reasons; raise calcium, lower, stabilize
alkalinity and raise the ph. The alkalinity has stabilized from 14 to 10 and my ph is at 8.2-8.3, but
the calcium has lowered from 350 to 300 today. I am aware of various scenarios regarding calcium
precipitation, just not 100% on them. I also have a calcium reactor but was not relying on it until my
calcium was higher.
<Mmm, I'd be firing that reactor over now>
My tank inhabitants are only snails, brittle stars and fish, but calcareous algae
and the optimum conditions are my first goal before adding more delicate corals.
Thanks, Dante
<Dante... don't know what else you have "in" the tank substrate, rock wise, but don't wait on hooking up, turning on the reactor... In all likelihood the simple addition of the carbon dioxide alone will solve your
low/er calcium issue. Bob Fenner>
Calcium level at 580
Hi there,
First of all, thank you for your time answering my question. I have a 120 gallon reef tank and it is a relatively young tank(4 months). I started using a combination of
Kalkwasser
doser (around 1/2-1 teaspoon/day) and Kent liquid calcium (2 caps(10ml) every day) along with Kent ProBuffer dKH(6 caps each day(30ml)) one and a half months ago. Before I used this method, my calcium level is 440 and I never checked it again until now. I was really
surprised when my test kit read 580. I don't have any alk test kit that measure the precise amount but I have the ineffective one from red sea marine lab. My alk reading shows high but it didn't give me any precise measurement. I uses pinpoint PH monitor and it shows a steady reading from 8.1-8.3. Please tell me what should I do now, I have lots of mushrooms, zoos, and polyp corals along with several fish. There are no sign of distress from my fishes and corals. My corals are fully open every day. Will this high calcium effect my fish and corals if I keep dosing like this.
<Calcium levels this high are not good. Stop dosing calcium right now and wait for the level to come down to 380-400, then continue dosing at a reduced rate. You will soon find the proper dose to maintain calcium at 380-400.>
I'm planning to stop using liquid calcium since I read in your website that it's not good for long term use, but how about my
Kalk, do I need to stop this as well until my calcium is back to normal level? Please tell me what I should do. and 1 more thing, what's the best PH for keeping xenia and polyp corals.
<The pH you are maintaining is fine for these corals. I believe the inexpensive calcium test kits have a difficult time accurately measuring the calcium ion we are concerned with. I think the Hach or
LaMotte kits are much superior in this regard. James (Salty Dog)>
R/O water treatment part2 2/22/05
One follow-up question: If I use B-Ionic, is there any reason not to use it to treat the ro/di water in the Brute, before that water is used to make synthetic seawater or to top-up the tank? Thanks, Tom
<B-Ionic and similar two part additives are shipped as two parts because mixing them will result in a useless insoluble precipitate. For this reason, they must be added
separately (I even suggest several hours apart), and cannot be mixed in make up water. Also, you could add one or the other part to your make up water, but IMO, this would be complicating a very simple process. Hope this helps.
AdamC.>
Something wrong with "articles" web server?
The last couple of days, I have tried to access various articles on the web
site (tonight I wanted to read the article on Kalkwasser). When I click on
the link, I get the "header", including the title of the article, but no
text. I tried to access several different articles, and tried from 2
different computers. Each time, the header appeared but no article.
Could the webmaster look into this?
Thanks!
Ken Baker
<Thank you for this note, reminder... we are unfortunately perennially behind...
in getting to actual writing of variously needed content (writing, photography,
graphics), but still need to "place" ongoing accumulations of "FAQs"... A pledge
to you... if you will write article inserts, to help you sell these to the print
and online 'zines. Bob Fenner, one of dozens of volunteers who are the WWM
crew.>
Re: something wrong with "articles" web server?
Bob--thanks for the reply. Just so I understand--you're saying that there
are titles for future articles in the listing of available articles, NOT an
issue of articles that exist that for some reason have come "un-linked" from
their hyperlinks and are lost in cyberspace?
<Yes my friend. Thank you for making this clear>
Thanks for all you and your dedicated team do. My immediate research has to do
with how to best dose calcium without going the ca reactor route--my aquarium is
in an open space between kitchen and family room (great for viewing from both
sides) but the cabinet underneath is completely full with skimmer, sump, and
small chiller. There is no room for ca reactor and it's not the kind of thing I
want on the wood floor next to the stand. The least unsightly of the bunch is
the chiller, so I may be able to move that outside the cabinet if I can find a
reactor that will fit in the space that frees up.
Thanks again
Ken
<Ahh, perhaps the next system. The best alternative for the majority of systems,
aquarists are "two part" solutions... either home made or store bought... that
include in one part, the actual alkaline earth materials (mainly calcium and
magnesium... perhaps with a touch of Strontium), the other the alkalinity
component (carbonate, bicarbonate/s...) and other material for keeping all in
solution... Much more "complete" than Kalkwasser et al., and much safer, easier
to use... There is much "difference of opinion" on this topic (even on WWM!) as
you will likely see... it is obvious that you are able to discern fact... and
make up your own mind. Bob Fenner>
- New PinPoint Calcium Monitor -
Hello guys, have any of you used the new Calcium Monitor from Pinpoint (retails for $249)?
<This item is very new and unfortunately they don't send me new products for testing so no... I haven't used it.>
Any ideas on how long the probe will remain accurate (just the replacement probe is $199)?
<No idea at all, but like any monitor probe, I would suggest that you clean it often. Many probes go south prematurely because folks leave them in one spot for as long as they last. But man, that is an expensive probe. Think of the number of calcium tests you could buy for that... knowing the calcium level from minute to minute seems excessive, perhaps even obsessive/compulsive to me, although I'm sure there are some out these who've already
snatched these up. I'm going to stick with my titrations.>
Thanks, Franz
<Cheers, J -- >
Calcium Query?
Hi guys,
My tank is running beautifully, but I have a question about calcium.
Stats:
40 gallon
Temp: 78
pH: 8.5
KH: 8dKH
Gravity: 1.024
Ammonia: 0 mg/L
Nitrite: 0 mg/L
Nitrate: 5mg/L
Phosphate: 0.25 mg/L
Cu: 0 mg/L
Ca: 300 mg/L
My tank is almost 6 months old (Day 178). I have 40lbs of Live Rock, clownfish, 3 PJ cardinals, 1
Coris wrasse,
dwarf lionfish, 2 cleaner shrimp, xenia, moon coral, red mushroom, 2 feather dusters and some hermits and snails.
I mix my saltwater for at least 24 hours with aeration and heater. I use Kent Sea Salt and Kent OsmoPrep with RO water. I was originally (3
months ago) using RO water and Kent sea salt then realized that I should be using some supplements to raise my calcium levels, which were 320
mg/L at the time. I was told by my LFS that the OsmoPrep would raise my calcium, so I have
started to add to with every water change (10% every 10 days or so). I have done several water changes with the OsmoPrep and my
calcium levels are still dropping slowly, almost 10 mg/L a month. My question is, Should I be using a calcium supplement as well as the
OsmoPrep? Or should I be using another supplement rather than OsmoPrep that will raise my calcium and the trace elements I need to use RO water?
Thanks guys, Troy
<Troy, Kent Marine does instruct the user of Osmo Prep to add Kalkwasser or a liquid supplement for reef aquariums, so obviously the calcium present in the product is not enough for reef systems. James (Salty Dog)>
Specific calcium method
Sat, 05 Feb 2005
Hello,
I would like to start out by saying that you provide an extremely
valuable site for information. I have read days and weeks worth of
information here and it has been a tremendous help. I have read a huge
amount on calcium but I am looking for (and maybe this is unrealistic) a
"this is how you do it" answer for keeping calcium levels stable. I have
not really found a step by step answer, in other words if I go with the
Kalkwasser, how do I set that up and figure out how much to dose and how
often, for example, is that done continuously or a weekly thing etc. if I
go with a two part solution what is it, how is that dosed, and how much.
I know that I could probably get some of these answers on the bottles
but I don't want to just buy the different things so that I can read the
directions.
Is there any advantage with one or the other? If there is some place
that I could be directed to I would be more than happy to read all the
information but I just can't seem to find the specific info that I am
looking for. I tried to ask the LFS owner (all saltwater store) about
the Kalkwasser and she said that it was a pain in the behind and that
the delivery system is always getting clogged and it is expensive. (my
checkbook has already stretched farther than it ever dreamed it could,
so at this point I am quite willing to spend the extra money and not
skimp now, I want to do it right, and not mess things up just to save a
little money, does that make sense?) She sold me the Reef Advantage from
Seachem and said that would be fine. I have read that this would be fine
to raise it, but not to maintain it, that in the long run that is going
to cause more problems (calcium chloride?) and that is not what I want.
I have used it only when my calcium dips below 400 (380). When I do add
it, I mix with RO water, dissolve then drip into the stream from the
powerhead.
I know that my reef tank is only going to demand more as time goes on,
right now I have soft corals, and bubble, hammer and the like, I want to
get a clam eventually but LFS said that my calcium would have to be
absolutely 425 always, and I don't think that I am ready for a calcium
reactor.
I am sorry I am trying to keep this short. Real quick specs here: 75
gallon, 150 lbs live rock, Rena Filstar XP3 canister, a second one was
dedicated to RowaPhos for removing phosphates, turned off at the moment,
4 power heads, two that sweep, New AquaC Remora Pro, awesome, (bought
this because I could not get my nitrates down from 50, tetra test, just
bought Salifert, trying everything I can to get the nitrates down, now
down to 25) PH was constant 8.0 tried for a while to use Seachem Reef
Buffer, never moved from 8.0 (got new Corallife Aqualight Pro light,
*absolutely awesome* left glass lids open, PH now around 8.1 to 8.15
(lights, lid made the difference?) Nitrites <.03 Ammonia 0 salinity
1.025 PO4 .03 alk 2.97 (DKH 8.3) still can not understand why there
are two listings for alk/dKH on my test sheet (Salifert) this has
steadily went down, dKH gone from 11.5 to 8.3 over several months.
Calcium range over several months has been 375-425 most recently hanging
around the 410-420 range, doing a mix of Reef Advantage around once a
week or a little longer to keep it there. I absolutely, without fail, do
a 10% water change weekly with RO water from LFS. I add 2 caps of iodine
every Monday, 1 1/2 caps Essential Elements after every water change,
Phytoplex 1/2 cap every Tues. & Sat. was using Coral Vital on a regular
basis, but then one day it completely freaked out my old skimmer, tank
white with bubbles for days, and now I am afraid to use it.
7 fish, yellow tang the biggest of the bunch, two shrimp, 2 crabs,
several turbo snails, bumblebee snails and a few other small ones that I
don't know the name of, one sand sifting sea star. Feed Formula Two
flakes in the morning, frozen Mysis shrimp in the evening, to the fish
and the cup coral.
I think that about covers it, I again apologize for the length. I just
have two concerns, calcium maintained and nitrates. Also, I have noticed
that I usually do a gallon of RO water to top off, since the new light
has been up, every other day or so. I would like to do a refugium but I
have a whole other set of questions on that, I will save that for
another day. <I will try to answer the two questions you have concerns
with. Maintaining calcium levels with the least hassle would be to use
SeaChem's Liquid Calcium. For economics (money saving) buy the larger
bottle. This product is very good at growing coralline. I personally do not
like the two part mixes since every time I've used them the alkalinity would
always go sky high. Unless you can buy individual bottles of part one and part
two, I would stay away from them. All you need is the liquid and alkalinity
buffer. There is no automatic way of dosing to maintain a certain level. Every
tank is different depending on calcium using animals. The only sure way is to
test every other week and maintain. Dosing Kalkwasser is cheaper since a bottle
of it goes a long way, but like your LFS says, it is a pain in the behind. As
far as nitrates go, maintain the suggested 10% water change weekly and clean
your skimmer weekly, very important. Watch your feeding. Feed sparingly a
little at a time until the fish lose interest. You may want to put Chemi-Pure
in your canister filter. It will take organics out that a skimmer will
not. I've been using it with excellent results. James (Salty Dog)>
Thank you, your help is greatly appreciated.
Rhonda
Re: Specific calcium method
Sat, 05 Feb 2005
Thank you for getting back to me so quickly.<Good morning Rhonda, and your
welcome.> I may be misunderstanding something here. I see that the Reef
Advantage has calcium chloride but I
also have the Reef Complete liquid and it has the exact same ingredients, one
being powder one being liquid. Or is there a completely different Seachem liquid
calcium? Do I need to worry about the chloride over the long haul, and if not is
there any advantage with one over the
other when it comes to liquid or powder? <The product I'm referring to is called
Reef Calcium. It is in a calcium gluconate (polygluconate) form. It will not
raise your ph where as Kalkwasser, administered to fast, can drastically raise
the ph of the system. The advantage of reef calcium is that there is no hassle
i.e. mixing, dosing etc. I have used Kalkwasser in the past and found that
pumps and powerheads have a shortened life. After six months use, an impeller
in a pump was completely covered in a calcium skeleton. Kalkwasser is the
cheapest way to go for that matter. I guess the choice is yours. I really
don't think chloride based calcium is going to have any detrimental effect in
the long haul. James (Salty Dog)>
Thank you.
Rhonda
Our method of adding calcium - 2/2/05
I absolutely love this site.
<Awwww. Thanks. We love it too. A valuable resource for information.>
You are awesome... I currently have a 240 with some softies and some mushrooms. I use
Ocean's Blend two- part system for calcium.
<As good as any I guess>
Should I do this everyday or watch the levels?
<Watch the levels. I suspect that since you only have softies in the tank that the calcium level is likely stable>
Is this even a good way to get good levels of calcium?
<Well.....my favorite is......ready for it.......a water change! That's right.....a water change....>
Because I want to setup a 90 gallon that is mainly SPS and clams... Reading through your site a reactor is the way to go.
<A good consistent source of calcium with less daily fussing over the tank, but the absolute easiest way is to maintain the overall water quality by changing the water regularly. Keep an eye on the levels. As soon as they start to drop you could change the water 10-20 percent. Of course it really depends on how fast and drastic the change is. Sometimes a water change isn't enough>
But I don't really want to spend the money.
<Understood. Well, saltwater aquariums is not exactly the cheapest hobby, but a water change might be your best bet, second to
Kalkwasser in the freshwater makeup solution>
Will the two part system be enough for SPS with the addition of eco-systems reef solution?
<Yes, likely>
Thanks you so much....
<Hope this helps. Any of the above would/will work. Now, which is the most cost effective and the easiest for you to administer. Also, is the proper application for your needs. If a drastic change is needed then the two part is a good bet or if the levels drop due to lots of coral and clam use. One of the more stable ways and easiest to administer is the reactor. Lastly you can use water changes and
Kalkwasser in the makeup water if you like to fuss a little bit more but it is tried and true. I add nothing to make tank but makeup water (daily) and seawater (water change) I have an all
SPS and clam tank. Sorry for the long drawn out answer but wanted to clarify. Thanks for being part of it all! ~Paul>
Correcting High calcium, Low Alkalinity 1/22/05
Thanks.... you mentioned a large water change, how large should I go my tank is a 46 gallon...
<one or two 50% water changes in the next 7-10 days to get back to par before adding ESV>
...and it looks like I will get another yikes from you, I have used Oceanic since
I started this tank.
<Yikes! Hmm... in the sense that they are able to achieve the much touted "high calcium" levels by... er... cheating on the buffers (flat Alkalinity).
That's not necessarily a bad thing. Some people favor this... others struggle with it (ahem). ;)>
What brand do you suggest?
<Tropic Marin is the best quality hands down... and IO is the best value brand sea salt IMO>
I have read horror stories about IO that people have to dose their top off water and there
mixing water do bring up the balance to match there tank water.
<In my greenhouse of eight thousand gallons... I'd buy IO in 8K gallon mix pallets. Now that I only have a three thousand gallon
fish room, I use less salt. Heehee... to say that I have had a good experience with IO quality and QC over many tens of thousands of gallons of water in the last 10+ years would be an understatement. Its a good salt my friend... they are the industry standard>
So basically then by me dosing just the ESV 2 part mix, will not bring my readings of CA 420ish, pH 8.3, and dKH 10 - 12?
<it will... once you start with the same ratios, however low that might be. But if your ratios are off to begin with (as they are now... skewed by your sea salt)... the liquid going into the aquarium will not make the corrections... it is not omnipotent... just balanced. You have to pay more for the former ;) Anthony>
Best calcium to dose with?
I have 3 tanks set up right now, 2 reef of 390 gal and 455 gal as well as the
fish only tank that is 96"Lx72"Hx32"w I have been using Kalk for several
years now in these tanks, yet still no coralline algae growth to speak of, in
the
2 reef tanks the pH is 8.2-8.4, dKh 13, ca 450, No2 not detectable, No3 <10
Po4 not detectable NH3/NH4 not detectable, pumps are the same size on both tanks
2400gph I have 2 Huge protein skimmers that produces quite a bit but drains
into waste line, I have a Kent COM450 RO w/ DI that makes my water, 4 (400wMH)
above each tank. I still have a problem with Cyanobacteria every now and then
but my HUGE population of blue leg hermit crabs seems to keep it somewhat at
bay. Now the Question.... There is a pet store near me that specializes in salt
water that said I may need to change my calcium dosing methods????? he
mentioned a 2 part I think called ionic or something like that, was a Part "A"
and a
"B" both being a liquid... What would your suggestion be to the best calcium
to use? BTW most all of my coral (excluding that elusive Xenia) does very well,
especially the elephant ear mushroom that I got when it was just about 2"
across, now it is about 18"....would appreciate your input.<There are some sea
urchins that do gobble up coralline. Do you have any urchins? James (Salty
Dog)>
thanks
Bryan
<<Huh? Please see here re:
http://www.wetwebmedia.com/CalciumFAQs.htm
and the Related FAQs in the series (links at top). BobF>>
Calcium and Urchins 1/11/05
No sea urchins in the tank I find them to be quite destructive on the
corals.
<this is a common and mistaken reputation of urchins because the wring urchins
are usually purchased (rock boring short spine species, pencil urchins, etc.).
The best Urchins are Diadema... totally reef-safe, nimble, do not eat much or
any corallines, superb algae grazers, etc>
So what in you opinion is the best type of calcium to dose with, excluding
calcium reactors...
<common calcium hydroxide... its time-tested and true with more benefits than
any other form of calcium. Read more about it in our archives at
wetwebmedia.com>
had a bad experience with them once.. do not what to have
that again.
<its sounds like you knee-jerk react too easily my friend. Just because you've
been given bad advice about urchins and calcium reactors, doesn't mean they are
bad themselves. Calcium reactors are the single best and most reliable way to
dose calcium and raise alkalinity in reef aquaria>
Bryan
<best regards, Anthony>
Re: Calcium and Urchins 1/12/05 Antoine to JamesG
To help a bit on that question and for your future
reference, mate... your urchin guess was a bit of a
long shot, Most urchins are quite useful (critical on
the reefs for algae control and useful in aquaria). A
few of the mismarketed species are cheap and abused...
pencil urchins lean carnivorous (grazing benthic
animal matter more than algae), and a few of those
short spine black urchins (Echinometra and the like)
are rock boring! And yes... graze corallines. But a
bevy of others are very useful and reef safe... not
the least of which is Diadema for tanks big enough to
let one grow out.
Their problem is/was lack of corallines though... and
one great, reliable solution is Seachem's liquid
calcium (polygluconate). It is... heehee... useless for
coral growth IMO, but (!) it is simply outstanding for
growing coralline algae rapidly. You have my promise
that most aquariums that gets a 3 month dose of this
cheap calcium will be swimming in calcareous algae!
FWIW
Anthony :)
My crazy "reef" system (Calcium concern)
Bob (or whoever is answering today)
<A few of us>
Let me describe my current status of a 55g I have set up. It relies very
heavily on plant life (macros)
<Mmm, macrophytes are not "plants", but algae>
in an in tank refug, has two 4' utility fixtures overdriving 2x t-8 bulbs. Plus
two 4' utility fixtures behind point forward to light up the in tank refug (an
egg crate crammed in there about 3" from the back glass). Back tubes are 4100K
<This temperature/incandescence is too low... should be 5,500 Kelvin minimum>
3300 lumen, top tubes are t-8 6500k and actinic. I have Chaeto, Caulerpa
profilera plus some grape and a red grape. substrate is silica play sand, rocks
are silica/lava/quartz type base rocks.
<Am sure you've read admonitions re silicates and aquariums>
I also have an external sump/refug with a DIY filter box with crushed oyster
shells as filter media and some red landscape lava rocks at the
entrance/exit. A mag 5 provides ~ 5x water flow between the display and
sump/refug.
<Neat, sounds like a good DIY system>
Tank has a yellow tang (1 3/4 years), firefish, two wild caught gobies, watchman
gobies, two "Nemos" and anemone (both about 1 year). Corals include button,
zoos, yellow and green star types , frogspawn, a green leather, a pinkish/brown
star polyps, several green Ricordea, open brain (~ 1.5 years), a purple
gorgonian, and a dark green hard coral with small polyps. All corals are
opening nicely with nice polyp extension. the dark green hard coral has
experienced nice growth including several of my accidental frags.
I do no water changes just replace the evaporative water.
<Not indefinitely>
I use straight untreated tap water in all my tanks. but I do use cold water ran
for a minute from a faucet used many times daily.
Ph is ~8.4 just before light off and under 7.8 just before lights on. (aquarium
phar***** test kit).
Whew!!!! now for my question. I added the crushed oyster shells to get my
calcium up. the 55g and my 20l I use for macro algae culture both and 250-300
ppm calcium with the red sea test kit (measures 50ppm steps). I got a SeaChem
(sp) test kit and then added the crushed oyster shells. calcium rose over 6
weeks or so to 400ppm in the 55g. And has stayed there for at least 6
months. But the 20L macro tank with the same percentage of evaporation and same
substrate, has remained at under 300ppm Ca.
<The algae are taking up the alkaline earth materials.>
It seems to me that at least some low level of calcium buffering is being
provided by the shells. What do you think?
Bob
<See above. I wouldn't be concerned with the 300 ppm. Calcium if your system's
are doing what you want them to. Bob Fenner>
Calcium test kits?
Dear WWM crew,
Was curious if anyone there had experience with this brand of kit.
According to the dating on the package the reagents are within their shelf
life, but when I add the first step with my saltwater I get no color change
to blue? << And you are sure you should? Hmmm, I doubt it has gone bad. >> Any
help or a recommendation for a different kit would be much
appreciated! << I don't think you can go wrong with a RedSea test kit. >>
Thanks In Advance
<< Blundell >>
Test Kit Discrepancy 12/16/04
Hey folks, I'll cut right to the point (sort of). I have a Lamotte Ca test
kit. I have two Salifert Ca test kits. The Lamotte indicates something like >800
ppm. The Salifert shows less than 200 ppm. Now I just realized today, after
months of using the Lamotte kit that it measures CaCO3 (calcium carbonate) which
isn't the same as just free ion Ca (right?). <Well, I will be totally direct...
maybe. Sort of. Is your LaMotte test kit a harness kit or calcium kit? It
sounds like it is a harness kit which would measure all hardness metals (Ca and
Mg mostly) and give you a result AS IF all of the hardness was from calcium. I
would trust the Salifert, especially since they agree with each other. It is
also possible that one of the reagents is bad.>
Ok. I previously bought a Salifert Ca test kit when I started getting the really
high Lamotte kit readings. This (the Salifert) should just measure Ca ion
concentration, right? I thought the Salifert was wrong when I started getting
readings of 190 ppm over the past couple of weeks. So, I bought another Salifert
test kit. I got the same readings as the first Salifert, which is OK and sort of
a relief for me to know that at least the kits are accurate with respect to each
other. <Salifert test kits are know for good quality, but also for subtle, hard
to see color changes. I can usually see the color change best in bright natural
sunlight and often get verification from my wife.>
I started to throw out the Lamotte Kit when I read that it measures CaCO3 not
Ca, which would make the readings seem substantially higher, right??? So maybe
the Lamotte readings of 800+ are actually OK since it's not just measuring Ca by
itself.
<The kit is probably fine, but it is not measuring what you expect it to.>
Is there a formula to determine the amount of Ca (in ppm) from CaCO3 reading or
a table to cross reference the readings? Should the CaCO3 be around 900 or so?
Is my thinking outta whack? BTW, my alkalinity is 12 dKH (Salifert test).
Thanks, Randy <There may be, but you would probably have to measure the Mg and
subtract which would probably defeat the purpose. Best Regards. AdamC.>
Calcium too high - 12/13/04
Good morning, <Hey>
I'm having a some trouble with my calcium levels in my 10 gall nano tank. I just
cant drop it down to 420 ppm. <Where is it at?> I add the maximum recommended
dose every day and it still doesn't drop. <Dose of what?> My tank has been
running for 1 month and I had it at 420 before but then it went up. What could
this be??? <Could be a lot of things. Have you looked through our FAQs on
Calcium? See here:
http://www.wetwebmedia.com/Calcium.htm and here is a topic that needs
understanding
http://www.wetwebmedia.com/calcalkmar.htm. Do regular water changes with
good quality RO water and a quality salt mix. Try a Halimeda algae as well. This
tends to use up a lot of calcium in its growth process. ~Paul>
Thanks for your time
Ca too high?
Hi Crew,
I have been attempting to raise my calcium level for several months but I
could not get above about 400 ppm, using my Hagen test kit. I use a Nilsen
reactor to dose Kalkwasser for all makeup water and I have been adding
Seachem’s Reef Advantage Calcium occasionally also. My alkalinity typically
remains low as well (~ 3-4 meq/L), so I dose with baking soda and
occasionally with Seachem’s buffer.
<< Just raise your alkalinity and don't worry about the calcium. >>
Last night I discovered that my Hagen Ca test kit was empty so I just
purchased a SeaTest kit and, to my amazement, it just reported my Ca level
to be 570 mg/L!!! Does this sound possible? << Absolutely. >> With the low
alkalinity
(currently 2.5 meq/L) I can understand that Ca could possibly be at an
elevated level but 570 mg/L sounds unbelievable high.
<< Not unheard of at all. I've had tanks with Ca over 1000 mg/L. >>
I had also assumed that my Ca level was low because, although my aquarium
has been established for nearly 2 years, I have been unable to grow
coralline algae in any significant quantity. I was just beginning to see
some increase coralline growth but then it turned white and began to flake
off. << Usually more of a problem with alkalinity, or maybe even lighting. >>
Here are my tank stats: 180g tank + 50g refugium (DSB + Caulerpa &
Gracilaria), Temp=78F, Salinity=1.024, pH=8.1, Ammonia=0, Nitrite=0,
Nitrate=2 ppm, PO4=0.02 ppm, about 10 small SPS corals + 5” squamosa clam
for Ca demand, several fish.
What do you recommend? Should I attempt to dose more carbonate or am I in
danger of precipitating all my Ca? Maybe I should dilute my tank water by
50% and re-test (multiplying test results by 2)? Water change??? What do
you think?
<< This is so simple you won't believe it. Do nothing! Your tank is
fine. People strive for Ca that high. Stop adding things and just do nothing
for 8 weeks. >>
Thanks for the help!
--Greg
<< Blundell >>
Calcium too high?
Hello WWM Crew,
I read your archives for hours looking for a problem similar to mine
before writing because I am sure you are extremely busy. I found some
that were close, but not exactly the same so here it goes. I have
tested my calcium ever since the tank was set-up which was May of this
year. Recently (the past month or so) the levels have read about
640ppm. I wasn't sure if the test kit (SeaTest) had gone bad so I
bought another one today (Salifert) and tested the water. Same
results
as before, Calcium above 500ppm. I tested the Alk (Salifert) and test
results showed 2.63 meq/L, and the test kit recommend 2.9. The kicker
is that I have not used a calcium supplement (B-Ionic 2 part) for about
two months now. The only supplement being added to the tank is
EcoSystem Reef Solution and I emailed those folks and they said it did
contain some calcium but, not enough for a tank with LPS/SPS or clams.
The coralline algae is growing like crazy, even on the glass,
thermometer, heater, etc. I have done water changes of about 25
gallons
(100 gallon tank) with RO/DI water two or three times and the levels
will not go down. << Great, stop trying to lower them. >> I use
Instant Ocean salt and I understand that the
salt has calcium in it as well, but enough to keep raising calcium
levels in the tank? I have four LPS corals, a couple of softies, 120
lbs live rock, and nine fish (gobies, tang, clowns, Chromis). Please
let me know how I can bring the calcium level back down to an acceptable
range. << Here is what you should do. At least what I would do. I'd
start adding or dosing a buffer solution. Like one half of the
B-Ionic solution. It will really help to raise your alkalinity,
allowing more coral and coralline growth, bringing down your calcium. >>
One more question, I recently added the large CPR AquaFuge to my
tank and added a Caulerpa algae pack (looks like feather) to the
refugium with Kent bio sediment and a few pieces of live rock. It has
been running for a week now and I have left the refugium light on 24/7
because I read that the Caulerpa would not go sexual this way. Is
this
true? << It may be true, but I still just leave my lights on at night.
>> Mine seems to be going sexual (turning white and gooey) and dying
off. Are there other algae species you would recommend? <<
Caulerpa racemosa, the kind that is unfortunately called "grape"
Caulerpa. >> It doesn't
seem to be growing for me and I hear it is a relatively hardy species.
Sorry about all of the questions, but after these are answered I will
have a little bit better understanding of what is going on in my tank (a
never ending battle it seems). Please let me know if you need anymore
details in order to make an accurate assessment.
Thanks For Your Great Website,
Luis Curro
<< Blundell >>
Ca too high? continued
Thanks for the response Blundell! Earlier today I did dilute a sample of
tank water 50% with RO water and repeated the Ca test. This time the
reading was 465 ppm. So there does appear to be some variation with this
test but, in any case, it sounds like either reading should not be cause for
concern. << No, no reason to worry at all. >> I did just buy Seachem Reef
Calcium since I read on WWM that this
has delivered good results at establishing coralline algae. I guess I will
just wait to use it now though.
<< Good idea. >>
Since my Nilsen reactor is connected to my top-off water (via a float switch
and a solenoid valve to my RO filter), do you see any problem with leaving
this connected as-is? << No that sounds fine. >> I am assuming this should not
overdose my tank with
calcium - correct? Lastly, I have never had a pH reading over 8.1, even
with 100% Kalkwasser makeup water. Does this indicate a root cause I should
be trying to identify or should I just continue dosing (or increase dosing)
buffer? << Well I don't think you can really over dose buffer. Okay, you
certainly can. But most people neglect this area and just add too much
calcium. I think you are fine, and if your reactor is adding calcium and buffer
it will add them in a balanced portion... which is what you want. So I think
everything is fine. >>
--Greg
<< Blundell >>
DSB & Calcium
Hello WWM,
<<Hi there>>
I have two questions the fist being. I have a 90 gallon reef tank that has been
set up for 9 months. I have about an inch of live sand as a base. I was
wondering since I have quit a bit of live rock and soft corals, is it too late
to add a DSB? Everything in the tank is starting to look really good and would
not at this point want to mess it up. I'm not sure if moving all that rock with
corals attached would cause havoc on them or would it be worth the risk from the
long term benefits? Also If I use sugar sand can I pour it over my live sand
that is a little more course?
<<Fishkeeping is subjective, so the answers to these things depends on who you
ask :P I have had no problems with deep sand beds. Thing is, they DO need to be
maintained (water testing needs to be done regularly, so you can foresee any pH
etc, problems and remedy them) You don't want your sand bed to become
supersaturated with organics without your knowledge. There is plenty of opinion
in forums here about DSB's, read on! If you have a sump, you can put your Deep
Sand Bed there. That way you will not have to mess up your reef structure: this
is beneficial for a few reasons: the ease of installing it, maintaining it, an
removing it if you change your mind further down the road. Another idea is if
you have enough open space at the front of your tanks rockwork, you can try
adding the sand at the front of the tank only, and just letting it drift back in
between the rockwork. If you add sugar sand, you will not need as deep a bed,
three to four inches should be more than sufficient, and you can stir in gently
into your older sand. Once you do add the new sand let it sit, do not
disturb it unless it's necessary. It will take a while before the new sand bed
becomes a nitrate reducing machine, so be patient. I prefer the idea of putting
it into a sump, though. Just seems easier.>>
Second question is about my calcium levels. They seem to be quite high around
550 with Alkalinity at around 3.0 -3.5. I was trying to get coralline to grow I
might have over done the Calcium a bit. Even after three water changes using
Tropic Marin salt the levels have not come down much. I was using Seachem's Reef
Complete & Reef Calcium. But I have not added any of those supplements for over
a month?
<<First, you might want to try a different calcium test kit, just to verify your
previous results. And take a water sample to your LFS so they can test it also,
and compare results with yours. Your alkalinity is too low. Is your pH also low?
Is your pH stable? Does your tank have good circulation? All things must
balance. Please do some more water changes, to lower your calcium to approx
400-450 max, and use your products to keep your Alk and pH stable, if necessary.
And, as always, do so gradually.. Please make sure of your test results before
adding anything. You should use good test kits, and you should be as precise as
possible when doing them. Keep a written record, and remember that a relatively
new set-up such as yours can show normal fluctuations. Just be sure they are
accurate ones, so you can react accordingly. Keep on testing :)
-Gwen>>
Thanks again for your help!
<<Welcome>>
- Time for a Calcium Reactor? -
Hi, I am currently setting up a 120 litre marine fish only aquarium. It will
have a sufficient protein skimmer, an external filter, double T8 marine lighting
and an external heater. I am using Kent marine salt. Is it essential for me to
put regular calcium additives in the water, or worse, buy a calcium reactor. I
am worried as I am on a relatively low budget. <For a fish only system, you can
likely get away with semi-frequent calcium additions. Cheers, J -- >
Calcium Gluconate 1012/04
Hello, I sincerely appreciate the work you guys are doing.
<Thanks! We sincerely appreciate that you appreciate it!>
I have a question about calcium gluconate. I presume it dissociates in
saltwater to calcium ions and glucose or some other sugar. <It does dissociate,
but I believe that gluconate is metabolized by bacteria.>
If calcium levels are sufficient, could 't you just dose glucose if you are
trying to stimulate coralline growth?
<Hmmm... you could, though I am not sure how direct the effect is. The use of
simple organic carbon sources (sugars, methanol, ethanol, gluconate, etc.) may
provide some direct energy to corals and coralline algae, but the larger effect
may be the bacterial growth that is stimulated. The increased bacterial growth
reduces inorganic nitrogen as well as phosphate. Since phosphate poisons
calcification, reduced phosphate increases calcification. Some "magic potion"
products (think of those with cute little cartoons of the mustache and flipper
festooned company owner along side of wild claims in their ads) are thought to
work this way.>
(I note Moe and others using organic sources of carbon for denitrification, not
for coralline growth <Indeed. Methanol fed denitrators have been around for
along time, and the notion of ethanol (usually vodka or grain EtOH) is being
rehashed on the message boards as we speak. The long term efficacy and safety
of these strategies is questionable. If denitrification is the goal, natural
methods like deep sand beds work well. Even coil denitrators can work very well
without the need for organic carbon input.>
perhaps vitamin C or acetic acid would do the same for corallines?) Many
thanks! Charles Matthews MD <Craig Bingman wrote an excellent article on the
use of acetic acid to extend the solubility of Kalkwasser. He showed the
balanced chemical equations for the metabolism of the acetate that proved that
the net alkalinity was not different than the use of Kalkwasser alone. I
believe that he also stated (if not demonstrated) the same for gluconate. FWIW,
Vitamin C, or any of its forms (ascorbic acid, etc.) along with any other
anti-oxidant is a poor choice since their use can result in significant drops in
redox. Many aquarists have noted a poor response to additions of large amounts
of vit C or ascorbic acid.
The bottom line is that "tricks" like inorganic carbon additions are not
necessary when other aspects of system design and husbandry are
optimized. However, their may be a place for conscientious and thoughtful
experimentation! Best Regards! AdamC.>
Calcium Gluconate follow up 10/14/04
Thanks for your thoughts, Adam!
<Always a pleasure!>
I'm still unclear about whether the addition of calcium gluconate to seawater
differs chemically from adding glucose to seawater, since c.g. will dissociate
(ignoring the minor calcium issues? Charles <I am not 100% sure of this
either. There is no question that the gluconate will be safely broken
down. The net effect on any process is likely to be negligible. My big concern
with this as a source of calcium is the lack of alkalinity. If you are
otherwise maintaining alkalinity and/or wish to add some source of simple
organic carbon, then by all means go for it. Hope this helps. For the
definitive answer, check the chemistry forum at reefcentral. AdamC.>
Re: Add CaCl to water change?
Thanks Steve. <You're welcome. Sorry this follow-up is late.> I have tested the
fresh saltwater a couple of days after mixing and get 320ppm Ca @ SG 1.024 with
a Salifert test kit. <Odd, it ought to mix up more like 380.> When I do a
substantial water change after building Ca in the tank to around 380, it always
drops because the fresh saltwater is more dilute in terms of
Ca. <Yes, that would happen if adding 320.>Is there another brand of synthetic
salt that is higher in Ca? <IO should be. Perhaps you should contact Marineland
at their website and ask their opinion. I recently switched to the new Oceanic
brand and have been very satisfied. Many feel that Tropic Marin is the "gold
standard." I do run a calcium reactor, but as you know, that is more of an alk
generator than a Ca generator. I also buffer the RO/DI water with Super Buffer
before adding salt. It would make life more simple if the synthetic salt had
more Ca in it. <adding Seachem Ca would be quick & simple.> What concentration
of Cl is too much? <I am not aware of any specific numbers on this.> It looks
like I need to add about 240g anhydrous CaCl2 to 200 gallons to raise Ca to
400ppm. Regards, George. <Over time, I think you can keep your Ca up by adding a
bit to your change water. You could also try the other two brands I mentioned.
Oceanic is also usually priced very competitively and is available at most Petco
stores. Do contact Marineland. You could also start a thread on our Chat Forum
to see if others are experiencing this problem. Hope this helps. Steve Allen.>
Calcium test kit accuracy 10/03/04
I have read several of the FAQ's on calcium, and still have a question. I
have a 125g that I started Sept. 1. I added 125lbs of un-cured LR on Sept.
11. Euro-reef skimmer (in sump), fluidized bed. A lot of my LR has a white
coating on it - like a crust.
<assuming you have adequate water flow for curing rock (20X+ turnover of the
tank?), this may simply be decay from hard curing rock>
My calcium readings are off the chart (>500ppm).
<this seems very highly unlikely after even a few hours (without
precipitating).
Much more likely that you are getting a misreading from your test kit. Even new
kits can give false readings. Do take a water sample to a friend or the LFS for
a test of CA on a different type or brand of test kit>
I read about the possibility of a "snow storm" and it is scaring
the crap out of me.
<no worries... you would have to be/have been adding obscene amounts of Ca>
I changed 19gallons of water today, using DI water -
<yikes! now that is dangerous. Never, ever use/add raw DI or RO water. Always
aerate for 12+ hours then buffer 2+ hours in advance of salting or using for
evap water>
calcium is still off the chart.
<I see... all the more reason after using demineralized water to believe that
this is a misreading on your test kit>
I have only added Bi-onics only once. Today I just added the Alkalinity part
(part 1) in the hopes of driving the calcium down.
What to do?
<I'm as certain as I can be from here that you have a bogus test reading... test
again my friend. Anthony>
Saltwater Mix Deficient in Calcium (9/29/04)
For the last 2 months, I have been doing weekly 40% water changes using
Instant Ocean at SG 1.024, which produces a Ca concentration of 320ppm. <I would
have expected higher.> Obviously, if I exchange this with water from my tank,
which has 380ppm
Ca, the final Ca concentration in the tank will be less than 380ppm at the
moment the exchange is completed. In order to get the Ca concentration back up,
I have to add Ca in excess of the daily dose that satisfies consumption. I asked
this once before and the answer I got was that CaCl2 should not be dosed on a
long-term basis. I understand that adding CaCl2 to the tank over a long period
can cause problems with excess Cl, but how does that relate to using it to
adjust the concentration of Ca in fresh saltwater for exchanges? <CaCl2 not the
best way to go here either, for the same reasons.> For instance, if CaCl2 is
always added to increase Ca concentration of fresh saltwater from 320ppm to
400ppm, the Cl concentration of the tank will never exceed the concentration in
the fresh saltwater, or am I missing something? <But that level in the
replacement water will be higher than the desired Cl range for the tank.> If not
CaCl2, what is the best way to increase Ca in synthetic salt mixes that produce
lower than desired Ca concentrations out of the bucket? Thanks, George. <The
high-tech expensive way that people with high-Ca-consuming corals is a calcium
reactor to keep the Ca in the tank up. Another option is to just add the Instant
Ocean and then check the tank's Ca in a day or so and add a two-part supplement
like b-Ionic to achieve and sustain the desired Ca. Probably the simplest thing
to do: If using RO or RO/DI or DI water, be sure to buffer before adding the
salt. I like Seachem's Reef Buffer or Reef Builder. After the salt is added and
the water stabilizes, then bring the Ca up with Seachem's Reef Advantage Calcium
or Tropic Marin's Bio-Calcium. BTW, how soon after mixing do you test the Ca?
I'd give 24 hours to stabilize before measuring. Hope this helps, Steve Allen.>
Can switching salt cause calcium problems?
I have spent most of my day reading all of the posts re calc/alk to get
my head around this.
First some background .. I recently (2 days ago) had to switch from
Marine Environment to Instant Ocean (ME no longer being imported to
OZ).
Previous ALK was 10 dKH (JBL test kit) and Ca (sera) .. for the past
two days my ALK has been 12dkh and calcium 340 (same kits).
Other than the coralline algae the only other obvious calc user in the
tank is a Catalaphyllia.
pH is 8 - 8.2
My question is .. should I be concerned? << Or those levels different from
before? They seem fine to me, and I wouldn't worry. >>
Do I dose with a calcium chloride supplement or do I do a 100l (approx
500L) tank with Natural sea water? << I wouldn't add any straight
supplement. If I did add something I would add a two part solution, but
probably wouldn't do that either. >>
I know you must get tired of such questions but I don't know what to do
.... the calc chloride supplement will bring up my calc but stuff up my
ionic balance. << Yep, probably wouldn't do it. >>
Sincerely and thankfully
Grant
<< Blundell >>
pH, Alk ok, Calcium too high 8/31/04
Have spent hours reading your articles and just want to say thanks for
Anthony's one on elementary understanding of Calcium and Alkalinity. The
calcium in my 150 gallon tank is at 600. (Red Sea test). I used to dose daily
with liquid calcium as instructed on the Kent bottle. Stopped that back in July
when the calcium was over 1200! anyway, alk is 4 meq (11 something dKH) and ph
is 8.2. So is water change the only way to get calcium down? Since July we
changed 60 gallons, then 50 each two weeks. This is more that the recommended
typical water changes and I am concerned about whacking out all the biology just
to get control of calcium. The tank has about a dozen corals, 11 fish, and a
bunch of snails. 100 lbs rock and 160lbs sand (3" deep bed). Lesa <Your first
step should be to verify the results you got with a new test kit (different
brand). It is very unlikely that your calcium could have reached 1200 without
precipitating out of the water. I would also verify your alkalinity
result. Calcium supplements should only be used in conjunction with alkalinity
supplements in order to keep them in balance. If you verify that your test
results are correct, then water changes will help. Be sure to choose a quality
salt mix. Lastly, supplements should never be added according to the directions
on the bottle, but rather according to the results of your water tests. This
leads to my favorite Fennerism: if you aren't testing for it, you probably
shouldn't be adding it! Best Regards. AdamC>
Low calcium problems.
Hi crew,
<< Blundell here. >>
My new 120 gal tank has been running for a month now. I believe the N cycle has
been completed - ammonia, nitrite and nitrate all seen to rise and then drop to
zero. There are about 200 lbs of live rocks that were once covered by brown
algae but now these were cleared and replaced by green macro algae which were
developing fast. << Sounds good, but I'd still go slow. >>
One aspect of water condition that still is not under control is the dropping
Cal. Some common boosting means have been tried such as adding Kalkwasser,
calcium chloride and change of water. << I would try adding a calcium liquid
supplement. Two part solutions are Kalkwasser aren't really meant to increase
calcium, but to keep the balance. >> Only the latter two were effective albeit
very temporarily - Ca went up a little bit but could not sustain for more than a
day. The rate of dropping was about 20 ppm per day. << Wow that is an accurate
test kit. >> PH was stable at about 8.1 - 8.2, alkalinity was a bit high at 11
dKH and Ca today stands at about 260 ppm. << Good info to add, that
helps. First off, I'd say a large water change is a big helper. Also liquid
calcium and don't add any buffer (Kalkwasser). >> I have tested the magnesium to
be at 1200 ppm.
I would like to have your advice on what further I can do. Some additional
information for you - (I) I have tribased pelletized carbon and PH rock in from
HDL in my sump. (ii) some of the live rocks seem to erode as I saw some holes
formed. (iii) the only livestocks are a handful of small fishes which seemed ok
Regards
Philip
<< Blundell >>
Low calcium problems continued
Dear Blundell,
<< Yes. >>
Thanks.
<< No prob. >>
I've tried liquid Ca, measured a subsequent rise in concentration but found it
dropped again the next day.
<< Hmmm, odd. Definitely a balance problem. I would still think a water change
could be a bid help. >>
Since my tank is in an office environment, I begin to suspect whether the
excessive CO2 during working days is the culprit. << Boy that is hard to
believe. I guess it is possible, but still that would have to be a lot of CO2.
>> On a Saturday morning, without doing any supplement addition on Friday, Ca
recovered from 240 ppm to 320 ppm. Would it be poor ventilation resulting in
high CO2 content in the air that caused the problem. << I would either do a
water change, or do nothing. Seriously wait, and see if it works out. If it is
a CO2 or gas exchange problem, then increasing your surface water
movement/circulation can really help. >> Did you have similar experience with
your other clients?
One more phenomenon is the proliferation of turf algae in the tank which could
be caused by the abundance of CO2 in the water. Please advise if this
assumption is valid. << Excess nutrients, or as important lack of nutrient
removal. In this case a large protein skimmer can help with both gas exchange
and nutrient removal. >>
Could ozone injection into the sump be effective in curing the Calcium depletion
. << Wow that is going out on a limb to get an expensive piece of equipment. I
wouldn't go for that. >>
Regards
Philip
<< Blundell >>
How do I get my calcium up?
Hello,
<< Good morning, Blundell here. >>
Thanks for all of the info that you provide and thank you in advance for answering
my question.
I have a 55 gal SPS Coral and Clam reef, all water parameters are excellent except
calcium. I am currently using ESV B-Ionic (daily) at the maximum dose and
I can't get a calcium reading above 320 on a Salifert test kit and a secondary reading
of approx. 300 on a less accurate kit. (I figured that I have a total of 40
gal of water in my 55 gal with refugium.= 40 ml of ESV daily.) My corals are
growing like mad and obviously using up the ESV product. I do not add other
chemicals to the tank, as I do frequent water changes using Tropic Marin salt. I
know that the logical thing to do would be get a calcium reactor, but, I am leery
of the gas cylinder that must be used (leakage). Also, I don't want to start
drip dosing Kalk as that would probably throw everything out of whack. Is
there anything else that I can do to bump up the calcium and still use the ESV product?
<< Absolutely. First, test your alkalinity! Many people who have this
problem you are describing end up fixing it by simply using half of the ESV product,
and not adding alkalinity. You need to get them balanced first, then add them
in equal proportions. If they are already misaligned then by adding both parts
won't really help. Well it helps, but you would be better off getting the
levels on the right track first. >> ESV seems to keep everything in good balance.
My LFS suggested Aragamilk or liquid aragonite, but, I'm not too sure that they
would do the job. << Hmmm, well I would rather use some liquid calcium instead of
the liquid Aragamilk. >>
Other info:
Filtration: Fishless Refugium with skimmer, approx. 85-90 lbs live rock
& DSB
Fish: a few Clown Gobies and 2 Dartfish
Critters: Various snails, 2 cleaner shrimps and few tiny hermits
Feeding: Frozen Cyclop-eeze for corals and a few flakes for fish (sparingly
on the fish food)
Any additional info that you can provide would be most appreciated.
Thanks Again,
Cheri
<< Blundell >>
Reef Water Chemistry - pH and Ca high 8/1/04
Hi--I have a 175gal tank with about 350lbs live rock.
<as an aside... seeing that you have a nice beefy supply of live rock here (very
fine at 2 lbs per gallon), I wonder if you have the rockscape built so that no
pieces are touching the vertical walls? If so, its a common mistake and one that
significantly impedes water flow around and through the reef. It causes problems
in time as detritus accumulates in inaccessible places. Do consider if this is a
problem>
Have not successfully been able to keep coral yet--they do not like my water,
but fish are well. My question is about a high pH reading (8.8 tonight--has been
around 8.2 - 8.4) and a high Ca reading 480ppm.
<pH is likely a non-issue... ideally it should be 8.4-8.6. The Calcium is
getting scary high though. I suspect too that because of it, your alkalinity is
flat or low (under 10dKH). Regardless... it is this way because the source water
is mineral rich, or you have misdosed (excess or imbalanced) supplements. Please
do look into our archives for the article called "Understanding Calcium and
Alkalinity" and follow the related links on the page>
Ammonia, Nitrates and Nitrites are all 0.
<you will want to allow a small amount of nitrates (5-10 ppm) to linger in the
future for optimal coral health and color>
Our alkalinity kit hasn't arrived yet, so don't know about that. We are doing
the Kent Marine Tech CB (part A&B). Do you know what could have caused the pH
spike?
<if you do not shake the 2-part supplements vigorously before every use, they
can be dosed imbalanced. Or... if your chemistry was not balanced before you
started using the 2-part supplement, then the imbalance was simply carried along
(the 2-part mixes cannot magically correct and imbalance... they ARE balanced
and need to be finessed relative to your chemistry and what your tanks daily
demands are)>
I skipped adding the CB solution today because Ca is so high.
<very good>
Is this harmful?
<necessary>
What other tests do you recommend? I also tested for Copper and that was at 0.
Thanks! Janet
<do get a good reef book on hand my friend. It will be money much better spent
rather than killing another coral. Eric Borneman's Aquarium Corals is excellent
for livestock/pictures... and if I may say so, my Book of Coral Propagation has
a very easy to understand section (most of the first half of the book -450
pages) on Reef Husbandry, water quality, etc. Best regards, Anthony Calfo>
- Spontaneous Calcium Carbonate -
Hi, Hope all is going well there. <Last time I checked...> I have a
question about stored water. I have a 55 gallon Rubbermaid container that I use
to store water in for water changes. When full this usually lasts
about 7 weeks. After buffer and salt are added and mixed I usually
keep a powerhead in the water running continually. I have read that
this can cause the water to lose carbonates and form calcium carbonate, and that
after mixing water for about 2 days the water should go in dark storage. <I,
on the other hand, have not heard this. Calcium carbonate is typically formed by
the addition of CO2 gas directly into saltwater and a bed of aragonite which is
the primary way calcium reactors work. Is the pH of your water dropping - is
there some other factor which is leading you to believe this is actually
happening?> My water container sits out on my screened in porch and I keep
the can covered. I have no other place to keep it. In the summer the
water temp gets into the 90s and I am scared that if I discontinue the constant
aeration the water will go stagnant. <You are correct... I'd keep up the
aeration.> Please advise me on what to do. thanks,
James
<Cheers, J -- >
Calcium supplements for Coralline Algae 7/13/04
I've ever read and if I'm not forgot, Cliff W. Emmes also mention that CaCL
is better to use rather than CaOH, it was said that CaOH will spike ph to very
high value, but CaCL will not spike ph. Which one is correct?
<do check/look for the copyright of the literature that you found that in, my
friend. I strongly suspect that information is 10-20 years old. We have learned
a lot about calcium supplementation since then. Calcium Chloride does raise
calcium without raising pH... but does so at the expense of imparting Chloride
ions that accumulate in time and can wreak havoc with water chemistry. You could
not do enough water changes practically to dilute this impending problem.
Again... CaCL is to be used as a temporary fix for low calcium. The fact that
CaOH raises pH is in fact a benefit (and a big one at that). Dosed at night when
pH naturally falls, Kalkwasser neutralizes acids that would otherwise be a
burden on Alk. This is how CaOH supports high Ca and high alkalinity.>
you said that I must choose better calcium, can I skip to CaOH or use the
commercial product like Kent marine liquid calcium?
<liquid calcium products are most always Calcium Chloride. Since most
hobbyists leave the hobby in less than a year or two <sigh>... not enough
people appreciate the risks of the long-term CaCL use.>
But I prefer you suggest me a DIY calcium solution, as commercial product will
cost a lot of money in long term.
<a calcium reactor is your best long-term solution... but simply calcium
hydroxide is fine or better in the meantime (other than tedium of dosing
manually... but for this, please do a search for "Kalk slurry method"
in our archives with the google.com search tool on our home page at
wetwebmedia.com>
What will happen if Mg is not that high?
<you will notice poor coralline algae and macro algae growth for starters>
I've been given by my friend a Kent marine reef starter kit which include Kent
marine strontium plus molybdenum, Kent marine liquid calcium and Kent marine
iodine.
<FWIW... I do not have very high regard for Kent marine products>
I've read also that strontium is very important for coralline algae,
<yes... there is strong anecdotal evidence of this (Spring/Delbeek, Wilkens,
etc.)>
it is also state in the Kent marine brochure that their strontium product will
promote coralline algae, so is that correct that strontium is so important? How
about iodine and what is the useful of iodine?
<iodine is very important for many forms of marine life. I recommend small
daily doses of iodine>
Thank you very much. Hengky.
<please do make use of our extensive archives my friend... you could answer a
lot of these questions yourself by taking the time to read and you'll learn so
much more in the process. With kind regards, Anthony>
- Kalkwasser Reactor vs. Calcium Reactor -
I'm trying to decide between a Kalkreactor or calcium reactor for my new
tank setup. It seems to me that their are advantages/disadvantages to both
methods. What worries me is the lower pH with a calcium reactor, but I've read
of some successes using the two together to balance the pH. <Calcium reactor
can be run by itself without adversely affecting the pH of your tank - and
likewise, Kalkwasser has a rather high pH - either one run alone and without
proper adjustment could cause trouble.> Any thoughts on which method is
better, or if using them together is ideal? <I prefer the calcium reactor if
choosing only one - the calcium reactor can also supplement trace elements which
Kalkwasser will not do. In the ideal world, it is better to run them both
together.> Also, is it true that fresh Kalkwasser must be mixed every morning
and added to reactor? <Not that familiar with these products - have never
used one, so I really don't know what the SOP for the unit is. Is my
guess/understanding that no, you'd leave the stuff in there to mix.>
Thanks!
<Cheers, J -- >
- Thanks, Now More Questions - calcium, algae...
thanks for the info j- <My pleasure.> another quick question! all the
algae in the tank was gone in one day as the angel had a ball after i added it!
so now am wondering, i just started to add liquid calcium to the tank it is by
Kent, it said to add 1/4 teaspoon a day up to 1 teaspoon a day everyday
depending on what specimens i had! <Hmm... best to follow these directions -
more is not always better.> will i have a calcium problem if i do this
everyday <At the levels you are adding, quite possibly.> {can you measure
calcium amounts? <Yes, there are several test kits available to the
hobbyist.> and do you need to? <Based on your haphazard method of adding
calcium, you should.> if so where can i go to get this? <At your local
fish store.> and since i run chem pure will this do any good or will this
suck up all the calcium in the chem pure! <No, I don't think ChemiPure will
do anything to the calcium you are adding.> i was under the impression that
adding calcium to the tank would help the shrimp molt and turbo snails grow
bigger shells. is this true? <Not exactly - through natural chemical
processes, there is almost always free calcium for your snails to use and in
typical snail fashion, they use it very slowly. The shrimp does not need calcium
to molt.> and the different algae would show up! <Really just
the pink and purple encrusting algae, coralline and the green algae Halimeda.
Other green, brown, and red algae are more like plants and don't require
calcium as much as other things like potassium, phosphate, and nitrogen.> by
the way it is so sweet to watch a cleaner shrimp go to town on cleaning my blue
angel, i like the cleaner goby, but the much thorough job is being done by the
shrimp, it makes me just want to stay at home just to watch this beautiful work
of art! am sorry i said just one? but here is another couple 1. i want to feed
micro stuff to my scooter blenny, can i buy this ghostly food somewhere?
<Scooter blennies - Dragonettes - need live food, which typically only comes
from large, well-established tanks. You will be hard pressed to keep this fish
alive if this is not your situation. Please read here: http://www.wetwebmedia.com/mandarins.htm
> and i am interested in taking home school to increase my knowledge about
the wonders of this beautiful hobby we are so blessed with, i want to do it
right , so is there a course i can take through email or something? <Better
to start investing in some books - start with Conscientious Marine Aquarist by
Robert Fenner.> once again am with everybody else this site rocks...
<Cheers, J -- >
- Bringing up the Calcium -
Hello crew. Question for you on my 40 gallon Breeder Salt Water
Tank.
Having Trouble raising my calcium. Measurements in my tank are amm,
nitrite, nitrate 0. PH 8.3 (day), 8.2 (night), calcium 325,
Phosphates .1, KH 300 ppm per test strip. <For starters, do try and get hold
of something more accurate than test strips.> I am kind of new at measuring
KH and dKH. My Aquarium Pharmaceuticals Freshwater Test kit says you
have to divide the KH # by 17.9 to get the dKH number. By this
standard my dKH is 16.5, that seems rather high though. For kicks I used the
freshwater test kit to measure my salt water number and came out with 12, this
is probably not right though. Please let me know if I am doing
something wrong here. <Well... typically there are different tests for fresh
and saltwater.>
Anyhow, I read several of the articles regarding calcium on this
site. Most were answered by Anthony. Anyhow, my KH is
probably too high and that is why I can't raise my calcium. <It would be a
limiting factor.> He mentioned doing weekly 25 % changes to help this
problem. Would bi weekly 10 to 15% water changes do the trick also?
<It might help, but there's no sense in rushing the process.> Just so you
know I have been trying to raise this using Kent A and B. <Hmm... two part
mixtures are by their nature balanced, which means calcium and alkalinity are
supplemented equally. I'd try using something else like Kalkwasser which is a
calcium-only addition.> I use Reef Crystals as my salt mix. Thanks
in advance for any answer you can give me.
Tom
<Cheers, J -- >
Re: Raising Calcium - Kalkwasser 6/9/04
Thanks for the reply J. You guys know your stuff. Have
answered a lot of questions just by doing searches on this site. I
will try using just Kalk and monitor my PH to make sure it does not get too high
on me.
<good to hear mate, Kalkwasser (Calcium hydroxide) is the most effective and
beneficial form of calcium dosing IMO. Best regards, Anthony>
Calcium Question
Hi Gang
<Hello, Ryan with you today>
I have a 90 gal reef tank whose calc wont get above 350. I drip Kalkwasser just
about every night. I have 2 questions. i have a sump/refugium below the tank and
I would prefer to drip into that. <OK>in the last compartment/return area
I have my carbon/Chemipure and my PolyFilter. Will this react unfavorably with
the drip??.<I would refrain from dripping here> I don't have a calcium
reactor, is it time to get one? <If you want this hidden from view, likely
yes. It's an easy DIY project if you're handy.> ?I eventually want to get a
clam so I need to get calk up. alk is near 4, dKH 11.5 (Salifert) my ph runs a
little low 8.0-8.3 and I cant seem to get that up either. I do 10% water changes
weekly. I have very few corals so far, so I don't think I have too much in the
way of calc drain by animals, although I have a ton of coralline all over the
back glass. <Sounds healthy to me! You're on your way to a successful reef.
Good luck, Ryan>
- Calcium Additives -
Hello....question here on calcium levels....Yesterday afternoon, I checked
my water parameters with Salifert Kit and the readings are as follow:
Calcium = 380, KH = 11-12 , ph = 8.2. So i figured i needed to up my
calcium levels a bit to 400 or so. I dosed 1.5 ml of Kent's
liquid Calcium into my 10 gallon nano reef. On the bottle, it says to
dose 5 ml to every 50 gallon but I figured that i would calculate the math and
dose 1.5 ml since i have a 10 gallon. A few hours later, i rechecked
the calcium levels and it went down to 365-370. <Wouldn't be so hasty...
would wait a little longer to test.> KH and PH still the same as stated
above. How come my calcium level did not budge at all. <I have a
hard time saying anything good about Kent products except that they have nice,
colorful labels. Typically weak concentrations... made to separate you from your
money. Would suggest you use a two part additive system like ESV B-Ionic.> I
believe that I have added enough liquid calcium for it to go up. Very
confused about this. What is your thoughts on this??? <Think that
a calcium level of 380 is pretty good - you'll be hard-pressed to find a real
reef anywhere in the world with a calcium level at 400 ppm.> Anyway, moving
on with my maintenance... the next day, i did a 10% water change (approximately
1 gallon), and checked my parameters a few hours later. Parameters
are still the same: Calcium 365-370, KH 11-12, and PH
8.2. So, instead of using Kent's Liquid Calcium this time around, I
used Tropic Marin's Bio Calcium... This time, my calcium went up to 400, so I
was happy. However, my KH also went up to 14-15 range (scratching my head).
<Why? Read the ingredients... I'd be willing to bet that the Tropic Marin
product contains buffers which balance the additive. Please read here: http://www.wetwebmedia.com/calcalkmar.htm
> PH still the same at 8.2... Is there any kind of buffer in Tropic Marin's
Bio Calcium??? <Would be a safe bet - read the label.> I think this has
happen to me twice. The last time was when I used it to raise my
calcium levels and my KH also went up. How is this possible???
<Think about it for a minute.> And how is it possible that Kent's Liquid
Calcium did not raise my levels at all??? <Because perhaps there's not much
actual calcium in the bottle?> This has also happened to me a few
times. Kent Liquid Calcium = no change, whereas, Tropic Marin's Bio
Calcium = Change but also change in KH. <Sounds like the Kent product is a
waste of money.> Oh, and the water that i prepare every week for water
changes has parameters of : Calcium = 380, KH = 10=11, PH=8.2 at a spg of 1.24 (refractometer)
using IO salt only (no additives whatsoever). Again, all parameters
are tested via Salifert kits. Thank you very much...hope you guys can
help me on this.
<Cheers, J -- >
- Calcium in Tiny Town -
Hi There!!! I have been reading the faq's on calcium and water
changes but can not find anything related to my problem. Hopefully
you can answer my question directly....I have a 10 gallon nano reef and has been
up for almost a year now. I keep my calcium levels at 400 - 410
(tropic Marin Bio Calcium) and my alkalinity at 10-11 dKH (all my parameters are
tested using Salifert Kits). My question is....every time I do a
water change (about 10% once a week which is approximately 1 gallon), my calcium
levels drop about 30 to 40 leaving me with 350 to 380 (Instant Ocean
salt). After every water change, i would have to add like 1 to 2
teaspoons of tropic Marin's bio calcium directly into the main tank to get it
back to 400-410 depending on how low it dropped after the water
change. What to do??? <Buffer your freshwater before you add the
salts - likely your makeup water is low in alkalinity and depletes the buffers
in your salt - the resulting addition to the tank pulls down the calcium.>
Should I add calcium to the 1 gallon premixed water (i just prepare 1 gallon
every week for water change) to get it up to 400-410 before adding it into my
main tank??? <I'd add buffers - if you've been doing your reading, then you
know these two are connected.> That means i would have to test my water for
the appropriate calcium level every time i do a water change before putting it
into the main tank. <Test the freshwater once for alkalinity - I think you
will find some interesting results.> I believe Instant ocean salt does not
give a high calcium when mixed. <No, it doesn't... it provides adequate
calcium, but not high levels of it - this is available in their Reef Crystals
brand.> So far, this is the best method that I can think. I am not
gonna go the Kalkwasser route because i am not a big fan of it so try to stick
with me on the supplement i am using. <Your tank is small enough that
Kalkwasser could be real trouble.> Cheers
<And cheers to you, J -- >
Calcium for LPS - 4/30/04
As you have been told a million times before, WWM is the BOMB <Da
BOMB> and there'd be a lot more fish in heaven were it not for your sagely
advice. Thanks! <Our pleasure>
I have a 75 gallon with a 30 gallon DSB sump that is nearly a year old. The tank
consists of several reef safe fish (clown, fire fish, coral beauty, gobies and a
tang), as well as several polyp types (sea mat, glove polyp) and a soft coral
(have never been able to identify it, but it looks like polyps, bright
golden-white in color but with 12 petals instead of the usual 8 on each polyp -
the petals look like little round white nubs), and a candy cane coral that was
recently added. I also have about 85 lbs of really good live rock and a lot of
macro algae growth in the sump (looks like hacksaw blades), <Caulerpa
serrulata> the tang doesn't touch it <Won't touch most Caulerpas as they
are usually quite toxic>
I do weekly water changes of 5 to 10 gallons using RO/DI water, my parameters
are perfect, the fish are doing great and the polyps and soft coral seem to be
growing and doing well. Somehow, when acquiring the candy cane, I didn't make
the connection that this is a stony coral. <Large Polyp Stony coral or
LPS>
I do not have a CA reactor. <Don't need one per se. If you had a many LPS or
SPS then maybe>
The candy cane seems to be much happier in my living room than it was in the LFS
(better lighting in my tank), <I am sure it is happier>
.. but I want to continue to ensure its happiness.<Good methodology>
I do not plan on stocking the tank further and will not be adding any other
polyps or corals. Should I be looking into a CA reactor? <Nope>
Or should I just test the water and add CA as needed? <Test the water and do
a water change if calcium is depleted>
Or should I just not worry about it and continue with regular water changes?
<Yeah, I like this idea better>
Also, on a completely different note, I am leaving for vacation in a few months
(Orlando - Discovery Cove!!!) <eeewww. Discovery Cove, in my experience, was
a rip off. I was extremely disappointed. You get little in return for the cost.
I invested in diving instead and now have unbelievable marine animal encounters
that are more fulfilling than anything that Discovery Cove could offer. Get
certified and spend your vacation dollars on a worthwhile vacation endeavor
someplace more exotic than Orlando with lasting memories of seeing a different
world than one we are used or one that is simulated for us in Disney World.
But........you will have a good time in Florida for sure. Look into diving!!!
You won't regret it.>
.. and I plan to have my family come by and help with feeding (premeasured
amounts) and top off (should only need to be done once or twice over the 10 days
we are gone). Although the DSB is teaming with life, the grain size of the sand
is in the 1mm range, and there are not a lot of larger meaty pods to get sucked
into the pump and put into the display for continuous feeding (there does seem
to be a lot of bristle worms, are they eating the pods?). <Possible but more
than likely they are feeding on any left over foods>
I was considering adding a Mysis starter pack, you know, 25 or so live Mysis
shrimp, to the DSB in the hopes of culturing live food that would hopefully get
sucked into the display regularly. <I like this idea. I do the same. I buy
mine from http://www.aquaculturestore.com/index.html
>
Would this mess up the DSB in any way? <nope. Be sure to feed>
Would the Mysis absorb essential coral elements in the water for their shells
and stuff? <Not enough to do any harm>
Is it a bad idea? <To the contrary, a great idea>
Am I crazy? <Not at all>
Any other advice you could give me regarding vacation settings? <Sounds like
you got it covered>
Thanks again for all your help! <No worries.....~Paul>
- Purple Rock not so Purple -
Hi Folks,
Once again, spending a late night browsing your great site.
I am in need of some quick advice. I have a 250 FOWLR with about 280
lbs of live rock. I would like the rock a bit more purple but cannot
seem to keep the level above 300 with my Tropic Marin Salt. I do 15%
weekly water changes and supplement tropic Marin calcium. I do not
like to use powders but will if need be.
Any recommendations as far as brand? <Yeah, I'd go for the two part
additives... specifically the ESV - Bionic.> Do I even need purple rock?
<Sounds like you do... really just an aesthetic decision.> I have angels,
a Naso and some wrasses.
Help me out if you would,
Thanks a ton,
Matt
<Cheers, J -- >
Trying to increase Ca 3/22/04
Thanks! Started by adding CaCl2 a couple grams at a time to 500L and did not
see an increase in Ca. Was afraid to add too much because of Cl issues but then
ran across a Web site calculator
(http://www.andy-hipkiss.co.uk/index.htm?http://www.andy-hipkiss.co.uk/cacalc.htm)
that said I needed to add a minimum of 40g in order to get close to 400ppm Ca.
How much Cl is too much? If I need to add 40-60g of CaCl2 to 500L, is that too
much Cl? I understand that I should not add CaCl2 to the tank over a long period
of time in order to avoid Cl accumulation, but can I us it as a routine
component of my fresh saltwater recipe (Instant Ocean) in order to raise Ca to
400ppm before a water change. Instant Ocean has been running 320-330ppm right
out of the bucket at SG=1.024. Regards, George.
<As per our earlier discussion, you can use as much CaCl2 as you need to
bring the Calcium up to 400 or so in the tank without concern for accumulating
too much Cl-. Just make the adjustment over several days to a couple of
weeks. Once you have achieved the desired level of calcium, the use
of a normal routine (calcium reactor, Kalkwasser or two part additives like
B-Ionic) along with water changes will keep you calcium and alkalinity in
line. Best Regards. Adam>
Trying to increase Ca 3/25/04
Okay, thanks for your patience. Based on what you have said and getting back
to my original question, adding CaCL2 as a standard ingredient to my fresh
saltwater recipe is acceptable because it will never increase Cl concentration
beyond the 20g/150L that is necessary to adjust Ca in fresh saltwater to match
tank Ca of 400ppm before a water change. Thanks again, George.
<Hi George. I think I missed the point of what you were planning
on doing. I would recommend against adding CaCl2 to your water change
water. I would supplement directly to the tank until you get the
desired calcium concentration. At that point, I would maintain Ca and
Alkalinity in the tank in a balanced fashion (Kalkwasser, calcium reactor,
two-part additive). If you maintain Ca and Alk this way, the slightly
low Ca in your salt mix should have minimal impact if you do typical regular
water changes. Hope this helps. Adam>
Trying to increase Ca 3/25/04
Sorry for a stupid question, but won't doing water changes with fresh
saltwater at 320ppm dilute and depress Ca levels in tank that starts out at
400ppm? I am running a reactor and dKH=11 (pH=8.2). Regards, George.
<Definitely not a stupid question, just a result of my lack of
clarity. I did not mean to imply that water changes would help raise
the Ca and Alkalinity, but rather that in addition to all of their other
benefits, they are an important part of maintaining the correct relative
concentrations of ions, particularly in cases like using CaCl2 for short term
calcium supplementation. Best regards. Adam.>
- Heater Scale Deposits -
Dear Crew:
Thanks for the great site. I am new to marine aquaria. I have two large tanks,
75G and 125G, which I maintain similarly and are 9 months and 6 months old,
respectively. Both have 300W submersible heaters. I found a heavy scale on the
heater of my 125 a few days ago. How long it has been there I am not
sure but there is no similar scale on the heater in the 75G. Here is a picture
of the scale in the 125G:
It is orange-brown and has spalled in places taking away with it the decorative
glass-stenciling. I am interested in what caused the scale to form because I am
trying to track down the cause of a prolonged micro-algae or phytoplankton
outbreak in this tank. <They are not related.> The calcium levels in the
two tanks are similar (around 500 ppm) but the temperatures are different: about
75°F in the 75G and 83°F in the 125G. Possibly the higher temperatures or
longer "on" times could have promoted scale formation in the 125G, but
I was also considering another possibility. I thought that the scale formation
might be due to my having left a floating glass-cleaning magnet in the tank for
two-weeks. <Nah... doubt that. The scale is simply just the product of a high
calcium level and the temperatures of the heater right at the surface of the
glass.> I had seen other people leave them in their tanks but I took the
magnet out after the algae or phytoplankton outbreak because I thought iron
might be leaching from it. <Not all magnets are made of steel...> I had
difficulty controlling the outbreak but eventually managed through water
changes, improved skimming and use of a canister filter. Do you think that
increased iron levels could lead to a runaway algae outbreak and produce the
scale on the heater? <No... that is just calcium and very normal for just
about any accessory attached to a marine tank and not regularly cleaned.>
Respectfully,
Karl
<Cheers, J -- >
- Calcium Addition Questions and More -
Dear WWM,
I recently purchased the 2 part B-Ionic solution (1 gal. ea.) additive for my
240 gallon saltwater system. I have over 200lbs. of Fiji rock mixed with a
smaller amount of Tonga branch live rock. <Very nice.> I have a few soft
corals growing on the rock although my tank is intended for fish only with live
rock. For filtration I run an oversized trickle filter (no bio-balls) with
standard foam media pads that are cleaned twice weekly, separate sump with deep
sand bed & more live rock. Instant Ocean salt mix is used and my current
readings are:
Specific Gravity: 1.026 using refractometer
kH: 10.2 Salifert test
Alk: 3.66 Salifert test
Calcium: 320 Salifert test
pH: 8.0 Sea Test
My question is, with my hardness and alkalinity pretty much within range, should
I just use the # 2 portion only? <No... is a balanced formula and both parts
should be added - just reduce your dose by 10 mg or so and go into maintenance
mode.> My pH is a little low as far as I can tell, so how do I raise pH and
calcium without raising the carbonate hardness and alkalinity with this product?
<Hmm... I'd be looking for reasons for the pH to be low - perhaps measure
more than once in a day - even in systems this large, the pH will shift from
high to low over the course of the day. Certainly, with your alkalinity in the
useful range, you shouldn't be having pH problems per se. Perhaps it is time to
add an algae sump and light opposite of your tank lighting - to balance out
pH.> In the future, can I just purchase the # 2 formula only to keep calcium
levels higher within the 400 - 450 range? <No. Would not do this and would
use Kalkwasser in this case, if all you want to do is maintain calcium - would
also help bring up the pH a little, mixed Kalkwasser being around a pH of
12.> My local fish supply store only sells it as a 2 part formula together.
It would seem that using Instant Ocean keeps desired levels of kH & Alk. in
check but not Calcium & pH. <Could be your source water is dragging down
the buffers in the salt - all other things being equal, IO salt is very
consistent, including bringing the pH to 8.4 unless your water is acidic. You
might want to test there, perhaps buffer before you add the salt.> By the
way, the readings above were taken 1 day after a 20% water change which is
performed once every two weeks. Interestingly enough, these are the same
readings I got 1 day before doing the water change on my tank. I am interested
in adding more calcium to my system to help the purple coralline algae
re-generate growing on my rock. <Don't go too crazy - the coralline will come
along on its own and in the meanwhile you'll spend a fortune in calcium
supplements. A little bit of moderation will go a long way.> I posed this
question to the folks over at ESV a week ago and they haven't responded, so I
have not added either formula yet.
Also, I recently received and added six 10 ounce units of Boyd's Chemi - Pure
from Doctor's Foster & Smith that I laid flat on the egg crate shelf below
the trickle plate in my wet/dry filter. As the directions tell you to do, I
rinsed each of the bags lightly after removing them from the plastic jar while
moving the media around in the bag until the amount of dust appeared to tail off
under the faucet water. Well, I must have got an extremely dusty lot because
even after rinsing these six bags for several minutes each, they still gave off
enough dust to make my water turn light grey and 3 days later I am still rinsing
my filter pads that turn absolutely black after just a day! Is this normal?
<Not in my experience.> The poor sponges growing in my sump and wet/dry
have become covered in this junk and I have attempted to blow them off with a
turkey baster as best I can without dislodging them. <This dust will move on
its own.> Luckily, my fish and soft corals don't seem to be affected by the
minute dust particles at this point. I remember using this stuff years ago and
don't remember it being this dirty. Last night I took them all out and re-rinsed
them all and they gave off so much black dust it was like they never were rinsed
at all! <Perhaps old inventory - would contact Boyd's directly.>
Obviously, I will do a more thorough job next time, but would the fact that the
package they came in sat out in 25°F weather for a day effect them in a
negative way that would make them give off dust, or I just got the bottom of the
barrel mix? <Do believe the latter.> It's the only 2 possible reasons I
can think of.
Thanks!
Joel
<Cheers, J -- >
Reef Calcium from Seachem 2/19/04
Personally I don't care too much what the stuff is. It comes from Seachem so
I trust it's quality, I test for what I add to the tank, and the stuff really
gets the coralline algae growing as evident in my tank and a friends tank that I
helped start up.
<very much agreed!>
So I guess my question is just to clarify your answer. No offence intended , I
am just curious as I like to learn. Kev
<none taken at all... thanks for the clarification. Anthony>
Copied from SeaChem's website
. Seachem FAQ
...A: No. This is a faulty assumption based on the premise that
Polygluconate is the same as glucose. Polygluconate is not a sugar any more than
cellulose is a sugar (it's a polysaccharide)....
Q: What exactly is calcium Polygluconate?
A: In chemical terms, it is a complex of ionic calcium and Polygluconate.
The end result for the hobbyist is that you get a more stable, more
concentrated form of calcium than can be found in Kalkwasser solutions (175
times greater than KW). It provides a unitary source of calcium and carbon
which has no impact on pH and is more bio-available and readily absorbed by
calcareous animals. For those who are even more curious, read on ...
Polygluconate is a long chain polymer of gluconic acid (the polymerization
occurs under high heat during product production). This creates essentially a
long carbon backbone with numerous hydroxyl groups that can participate in
complex formation with ionic calcium. In a complex the lone pair electrons on
the hydroxyl oxygens are shared between the oxygen and calcium, essentially
bonding the two together. When two hydroxyls participate this neutralizes the +2
charge on the calcium, creating an overall charge neutral species. In a chelate
there are many more bonds from the same molecule to the calcium such that the
calcium is surrounded (like a claw, "chelate" is
Greek for "claw" btw) and is held much more strongly owing to the
multiple interactions. Because cellular tissue is essentially "greasy"
it does not like to allow charged species to pass through it passively (e.g. oil
and water don't mix). Thus the requirement that special enzymatic mechanisms be
present to transport the required cations across the cellular membrane. By
masking the charge on the calcium, the calcium Polygluconate species is able to
passively enter cells through osmosis. The cells and hence the organism as a
whole doesn't have to "work" as hard to get the calcium it needs. The
resulting benefit to all of this is that because the calcium complex can be more
easily used one can either get enhanced growth at the normal calcium level of
400-420, or one can maintain calcium at 370-380 and not encounter
any declines in growth (while still seeing growth, just not as rapid as at the
higher levels). This is because the level of calcium complex that is present at
the prescribed dosing is essentially equivalent to a much larger level of ionic
calcium in terms of how much can be used within a given time frame.
Medical grade calcium carbonate 2/17/04
Hi, can I use medical grade calcium carbonate in my 75 gallon reef aquarium?
Thanks, Adam
<hmmm... check the chemical assay for impurities (what types) and then, what
are you using it for? Its not soluble for marine use (supplementation). Instead,
are you looking to simply use it as a substrate... or as Ca reactor media?>
Calcium problem 2/16/04
Hi I'm having a huge problem with calcium. I have some red sea calcium mix
which I have been adding ever Monday, Wednesday and Friday but it still hasn't
got the calcium above 300 (although my alk has been fluctuating between 15dkh
and 16dkh for the past few days). So I started adding about two cups a day
yesterday. I ran a test yesterday and my calcium was went up to 330.
Today I ran a test and the calcium was at 270!!!! I'm really stumped about this
and would love your help. Thanks, Kevin
<we have an extensive archive of FAQs and articles on many such subjects if
you'll take the time to read, explore and learn my friend. Do be sure to explore
the many links at the tops of the pages:
http://www.wetwebmedia.com/calcalkmar.htm
- Ocean's Blend -
Hi,
I would like to consult you regarding Ocean's Blend. I realized there a number
of people using this product and I would like to ask for your review about this
product before I buy it. Thanks.
Jim
<Well, Jim, I'd never heard of the product before now, so I looked it up on
the Internet. Seems to me to be at the least a calcium additive... who knows
what else is in it, they certainly don't say much. Personally, I'm always
skeptical of miracle-in-a-bottle type claims, but that doesn't mean I'm right. I
suggest you give it a try and get back to us - let us know how well it works, or
not. Cheers, J -- >
Trying to increase Ca
Greetings. I have a very lightly stocked aquarium (only one small SPS and a
couple of medium LPS, all are well) and I have been trying to adjust water
quality in anticipation of adding more SPS. Net system volume is 500L, pH =
8.24, 11.5 dKH, 340ppm Ca. I aerated a sample overnight and pH only changed from
8.24 to 8.27 so I guess that does not indicate a CO2 problem.
<All of those values sound fine except for the slightly low calcium. There is
nothing wrong with a pH of 8.2.>
I'm running a calcium reactor and I have been dosing a couple grams of calcium
hydroxide as slurry each day in hopes of seeing Ca climb. So far, it seems as
though I am only matching demand. Does that sound reasonable? Is that about one
should expect from so few animals, although there is a lot of healthy coralline
growth (rocks only, I keep it off the glass)? Do I need to buffer more to get
the pH a bit higher? Thanks, George.
<No need to worry about your pH. It really is fine, and definitely don't add
buffer. The reason your Ca isn't rising is because both Kalkwasser and your
calcium reactor add Ca and alkalinity in a balanced fashion. Without getting
into the background chemistry.... your alkalinity is already a bit high relative
to your calcium, which limits the amount of calcium that can stay in solution.
If you use some CaCl2 (Kent's Turbo Calcium is a readily available form) to
raise your calcium to around 400 and then go back to your normal routine, it
should stay there. Your alkalinity may fall a bit, but that is fine. HTH!
Adam>
- Encrusting Algae and High Calcium Help -
After reading your forums, I am in trouble, and I can't figure it
out. First off I have a 75 gallon tank, with a mix of 20 lbs of live
sand and 20 lbs of crushed coral, about 40 lbs of live rock (well sort of live),
A Marineland (?) Magnum 350 pro with 2 bio wheels, a Red Sea hang on Prism
Skimmer, 2 Rio powerheads, and 24" of airstones. The tank is
about 3.5 to 4 months old. I have about 16 or so hermit crabs, a
couple of lobsters, algae blenny, Foxface, sand sifting goby, 2 convict damsels,
and a cleaner wrasse. I feed them a cube of frozen brine shrimp and
about a half a teaspoon of flake food twice a day.
<A quick word of caution to you about your lobsters: they are not to be
trusted. Although they may make interesting pets, they are predatory and will
eventually kill a fish or two of yours. I kept a lobster many |