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FAQs on Marine Water Quality involving Nitrate Sources

Related Articles: Nitrates in Marine Aquariums, NitritesAmmonia, Establishing Cycling, BioFiltrationPhosphate, SilicatesNutrient Control and ExportDeep Sand Beds

Related FAQs: Nitrates 1, Nitrates 2, Nitrates 3, Nitrates 4, Nitrates 5, Nitrates 6, Nitrates 7, Nitrates 8, Nitrates 9, Nitrates 10, Nitrates 11,  & FAQs on: The Actual Science Re: NO3 Compounds, Importance, Measuring, Means to reduce: NNR (Natural Nitrate Reduction, Anaerobic Bacteria), Algae, Other Biota, Physical Filters, Chemical Filters... NitritesAmmonia, Phosphate, Silicates, Biological Filtration, Fluidized Beds, Denitrification/Denitrifiers, Bio-Balls, Wet-Dry Filters, R.O./Distilled/Treated WaterChemical FiltrantsDeep Sand Beds

Sources Short List: Excess foods/feeding, over-stocking, insufficient water changes/dilution, inadequate skimming, lack of useful biota, driven nitrification: Fluidized beds, UG Filters, Air-exposed "Wheels", Wet-Dry media, DLS media, sponges/filter pad media, canister filters, too large grade or not enough substrate, or LR...

Filtering a Marine Aquarium on a budget, Nitrate problems 03/27/2008
Afternoon Crew!
<<Afternoon, Andrew today>>
I wrote to you last week asking about compatibility and stocking for my 55 gallon Bow Front. To give the run down again, I have a Prizm Pro skimmer, a CPR BakPak skimmer, Aqua Clear 1200 powerhead, about 35-40lbs of live rock, crushed coral, and an Ehiem2215 Canister Filter. The inhabitants are 2 Ocellaris Clowns, 1 Yellow Tang (who's going to be moving in a few months), a Royal Gramma, 2 Skunk Cleaner Shrimp, 3 Peppermint Shrimp, and soon to be a Flame Angel.
<<ok>>
My questions is about my canister filter. I accidentally erased the response one of you sent me last week with the links to the information on the canister filters, but have done some searching myself on your site, and decided it needs to go. I do biweekly water changes, and after checking my Nitrates last night, I'm very concerned. If I remember correctly, the test strip read 260 ppm, or mg/L. PH is 8.1, Nitrites are zero, and I wasn't able to determine Ammonia, but I'm assuming zero since this set up has been running for over two years now.
<<Yikes !!!! ....Start of with, get rid of the test strips, they are highly inaccurate. Purchase a good range of liquid test kits like Hagen, API or Salifert and then test again to get a more accurate reading>>
I'm wondering what are some options for my set up besides the canister filter. I just started school and am on quite a budget, but also want to do what I can for the health of my tank. Plans are in the works with my father and I for a large (120 gallon) tank with 40 gallon sump, but until them a sump/refugium is not an option on this tank.
Could I just get rid of the canister all together, and if I do, should I replace it with anything? Can I just take out everything besides the two pouches of Chemi-pure and let it run like that? Are there any better filtering options for me?
<<I would slowly raise your live rock level to 55lbs and then slowly over the coming weeks, remove the canisters / hob filters and rely solely on the live rock to provide your filtration>>
Again, thank you for all you guys do for us. I'm an every day reader and I picked up Mr. Fenner's book before I picked up my first fish.
Sincerely, Heather
<<Thanks for the questions, hope this helps. A Nixon>>

Removal of a Tidepool II Bio-Wheel!! 3/7/08
Good Day Gentlemen,
<And ladies, hello Heath.>
I have a few questions for you concerning a Bio-Wheel out of a Tidepool II sump if I may.
<Sure.>
I have read on your site and have gathered that this Bio-Wheel could contain nitrates, or nitrate causing waste.
<The problem is detritus accumulation that would otherwise be exported out of your system, not that big an issue with the Bio-Wheels compared to bioballs.>
My first question is how much could it actually harm if it were a two year old system?? The reason that I ask this is because my nitrates are around 40 right now.
<Yes, high.>
I performed a 20% water change and it lowered the nitrates to around 30 for about 2-3 days, next thing I know, back at 40.? Obviously something is causing it.
<This fast a rise is likely due to feeding or stocking levels.>
Everything that could cause nitrates in the sump has been removed (blue-bonded pads, filter socks, old reactor media, etc.). The tank was recently moved (4 months ago) to my new home, so everything behind the rockwork was cleaned out as well. The only thing I could guess at is the Bio-Wheel, and if you guys will, please tell me if it could be the problem.
<Not this much, this fast. Take a look at your substrate and circulation, these are much more likely to be the culprits. The mechanical media mentioned above does have the benefit of exporting the detritus, if cleaned frequently.>
Here are the rest of the stats before I ask my other questions:
95g
125 lbs of LR
Tidepool II sump
Aqua C EV-120 skimmer
PhosBan Reactor w/Pura phosphate media
9 watt UV Sterilizer (don't know if this matters)
3/4" - 1" sand bed
1 ocellaris clown, 1 medium fairy wrasse, 2 PJ Cardinals, and 1 cleaner shrimp + various snails and crabs (small stock list for this size?)
1 bubble tip anemone and various small mushrooms.
Temp at 78 F,? ph 8.0 (a little low), SG 1.023, <Low also, shoot for 1.025-1.026.>
nitrates @ 40
I ran out of calcium and alkalinity test liquid...sorry for the incomplete info!
<No problem, not important regarding nitrate.>
I have 20lbs of additional cured rock (Marco rock if you've heard of it, it's completely bleached out? and dry) that just finished curing a week ago, even though it's having a diatom bloom right now, could I add it and curve any problems that the removed bio wheel could cause?
<No, dry rock is not live rock, it will take time to populate and become some semblance of live rock. With the amount of additional live rock you will be fine removing the Bio-Wheel.>
Third, what potential problems could I encounter from the removal of the Bio-Wheel and how do I prevent them? Fourth, how would you recommend removing the Bio-Wheel and what would you do to prevent any problems?
<You should have no problems simply removing it, I would simply take it out.>
I appreciate your patience with me and any advice that you may have for me. Unlike Bio-Balls, it's all or nothing with this wheel, and I would rather err to the side of caution in removing it.
Thank You Again,
Heath
<Welcome, thank you for writing. All will be fine with the live rock to take over. Scott V.>

Garlic Supplement (as Crypt trtmt.) and High Nitrates (rel.?)   02/19/2008
I have 30 and 75 gallon tanks salt water/reef set ups. A week after adding a fish to the 75, I noticed white spots this fish (only this fish). My LFS suggested soaking the food in "Garlic Guard" by Seachem. I would then feed both tanks with this food. The white spots disappeared within a week but the store suggested that I feed the supplement for a full month because if it was ick, the disease would come back in about a month.
<<Feeding a fish garlic will not fight or remove Ich. The fish needs to be removed and placed in quarantine and treated>>
I took readings recently in both tanks and the nitrates were high, extremely high in the 30 tank. Could the supplement be causing my problem?
<<If you feeding a lot, then, yes its possible>>
Since diagnosing the problem, I've drained about 20 gallons of water from the 30 gallon tank and intend to drain about the same amount in the next couple of days. Any other suggestions? Thanks.
<<Quarantine the fish, back off the feeding a little to once per day, or even once every two days. Continue water changes until nitrates are under control. Please read here and linked articles and FAQ's regarding Crypto http://www.wetwebmedia.com/ichartmar.htm >>
Larry
<<Thanks for the questions Larry, hope the above helps. A Nixon>>

Aqua Medic BioStars Flotor Query 11/23/07
Hi Gang, I love your website and use it daily with my ongoing trials of owning a mini reef aquarium!
<Hello Mark, Scott V. here. Our tanks can be challenging at times.>
I try not to take up your time by sending in trivial queries and like to just search for my answers on your site (I usually find what I need somewhere in there).
<It can sure be fun. There is so much information and a person can’t help but to learn a lot along the way.>
However I have a query about my skimmer / biological filter. I am currently using the AquaMedic BioStars Flotor which is a moderately priced but seemingly high performance piece of equipment. It is a motor driven protein skimmer with a biorotor biological filter. I have a 180 litre tank with 20kg of liverock and currently have 6 fish (2 percula clowns, 1 strawberry basslet, 1 yellow wrasse, 1 bluespotted puffer, and a Tailspot blenny). The skimmer appears to be working with a small amount of brown liquid being produced daily (I assume this is about normal for the amount of livestock I have). I have been testing the water every few days for the 3 months I have had the setup running and have had no problems until recently. The PH has been constant at 8.4, Ammonia has never risen above 0, nitrite has never risen above 0 and the nitrate (until recently) had been measuring at 0 also.
<Sounds good so far.>
Approximately 3 weeks ago I noticed the nitrate levels rising to 20ppm so I have been carrying out 20% water changes every 3 days with minimal success. The nitrates always fluctuate between 10 and 20ppm even after a change of water. I don't fancy carrying out larger water changes and understand a 20% every week or so should be fine.
<Should be.>
My question is this... does this type of filter I am using increase levels of nitrate? I have read that this type of filter is a nitrate 'factory' but didn't take much notice of these warnings until recently. Is there anything I can do to reduce my nitrate levels and should I remove the BioWheel from the housing? Thanks for any advice you can give on this. Mark
<I would remove the BioWheel. Your live rock will provide the necessary filtration. The wheel is probably contributing to the rise, but there can be other factors. If you were not seeing a difference in nitrate after your water changes then I would test your makeup water to see if anything has changed there. Also take a look at your substrate. Is it large grains and trapping detritus? Is there enough flow to keep the detritus from settling? Another thing to look at would be how much you feed. With the bioload on this sized tank you will see rising nitrate and must reduce/export it somehow. Either through constant water changes (which should happen anyway), through macro algae in a refugium or a deep sand bed. The BioWheel could very well be the culprit, but these are other factors worth mentioning. Your welcome, happy reefing Mark. Scott V.>

Re: Yellow Watchman Goby – 09/14/07
Bob,
<Paul>
Thanks again for fielding my questions. When you said "This may be a large part of the problem" What did you mean?
<Read here: http://www.wetwebmedia.com/fluidbedfaqs.htm
FBs can be nitrate generators par excellence>
The fish load is too small? Too great? The fluidized bed filter is a bad idea? I also forgot to mention that I use an aquarium pharmaceuticals Tap water filter for all my top off water and water making needs.
<Too slow, expensive... look into RO...>
Phosphate kit indicates "undetectable" I let the new mixed salt water age for a couple of weeks before use.
<Good technique>
I will do more frequent water changes, but to be honest I despair at it not working.
This is a very tough problem, and I feel like I am a very attentive and conscientious aquarist. I am not trying to create a "pretty thing" to look at, I love the animals and love the challenge of giving them a good home and I desperately want to succeed. BTW I made a contribution, it is the least I can do considering the wealth of info on the website.
Paul
<Appreciate this... When/where in doubt Paul, divert that time, energy to constructive purpose... e.g. reading. Cheers, BobF>

Fluidized bed: Should I pull it?   8/26/07
Gentlemen,
I have a 60gal/80lbs Cured LR/Venturi Skimmer/Fluidized bed/fish only system. Its been up just for a month and a half. I understand from your site, that FBD's tend to build Nitrates.
<Possibly... many systems have countervailing influence/s...>
1.Given my qty of live rock should I pull the FBD or its not going to harm me to keep it going?
<I'd wait and see here... perhaps the denitrifiers elsewhere will utilize the extra NO3>
2.On a different note, I see black algae growth on the back walls of my tank.
<Or, maybe not...>
My Turbos and Nerite are not eating them.
<Ah, no... is likely unpalatable... a mix of microbes, BGA...>
Are there any snails which would munch on them?
<Not likely>
And once again thanks for all your help!
Cheers
Gans
<Some valuable lessons here... I would be reading re Cyanobacteria on WWM. Bob Fenner>

Nitrate problems – 06/14/07
Hello,
<hello Christopher>
I've been reading your site since I started my saltwater aquarium about a little over a year ago. It has been extremely helpful in gaining an understanding of this hobby for me.
<Thank You glad we can help>
My problem has been that my nitrates do not seem to ever get down to an appropriate level. I recently did a 10% water change and I couldn't tell any difference in the reading from the day before.
Right now it is close to 40-50 ppm. I used a Hagan test kit for both readings.
I am really stumped on ideas. All I am hearing is feed the fish less, but I am wondering if there is another alternative. I feed twice a day, mostly flakes, pellets, but I alternate with Mysis and clips of algae. My phosphates are very close to zero on the Salifert test kit at about .03 (one over from zero).
Here is background on my tank:
1. I have a 150 gallon FOWLR with approx 120lbs of live rock with 4inches of sand depending (some fish move the sand around to make more room behind rocks)
2. Wet/dry filter to size
<Here is your problem>
3. UV sterilizer 18watt
4. about a shoe box size of Chaetomorpha algae in tank doing fine, grew from a baseball size. Should I use Caulerpa?
<Yes Chaeto is a great nutrient remover. I would increase light and duration over Chaeto so it grows faster and removes more.>
5. Water changes 15% about every 2 weeks. RO water is always used and gives zero reading on sticks for nitrate. I think PH starts fine from the salt mix (Red Sea), but never tested it at that point.
6. I feed them twice a day with flakes or frozen.
7. Fish and approx sizes are
a. Naso tang - 6",
b. Hippo tang - 6",
c. Majestic angel - 5-6",
d. Lemon peel angel - 4",
e. Red spot Pseudochromis - 2-3",
f. Yellow strip maroon clown - 5",
g. Juvenile Annularis angel - 3",
h. Tomato clown - 3",
i. 9 Blue/green Chromis - 2-4"
If you could assist on some advice on maintaining proper levels of nitrate, I would greatly appreciate it. I would like to get my water quality near perfect.
<The thing is here is that you are using a wet/dry filter which is an excellent biological filter for removing/converting ammonia and nitrite to yep you guessed it...NITRATE! These filters are referred to as nitrate factories and usually operate at nitrate levels over 100ppm. My advice to you is increase light and photo period over Caulerpa and remove the bio-balls or whatever media is in the wet/dry. Fear not...the biological filtration will continue with the liverock that is in the tank. You can use your wet/dry as a sump but remove the media that is in the tower section. Once you do this your nitrates will fall over the next week as they are converted by the bacteria within your 4" sand bed. Continue water changes because they are always needed to replenish trace elements and remove organic waste products from the system.>
Thank you in advance.
Regards,
Christopher
<Hope this helps-Rich aka MrFiremouth>

Raising nitrates, Feeding Tridacnids...  4/26/07
Dear WetWeb crew,
<Hi Joel.>
  This is my first time writing to you.
<Welcome to the show!>
Thanks for all the great information so far.
<Thank you for reading.>
  I'll keep to the point, my nitrates have been at 0 since cycling 12 months ago. All water parameters are within reef specs.
  The tank is a 90 gallon with a 16 gallon sump and 55 gallon refugium.
  I have 5 fish, 2 shrimp and about 20 snails & hermits, about 15 inches of fish total. Although everyone is healthy and growing, should I be feeding more or running the Aqua C EV-120 skimmer 12 instead of 24 hours per day? Also, I just tossed out very large ball of macro algae from the refugium called "Fire Algae" which I got free from Inland Aquatics and replaced with small amount of Ulva.
<Sounds like a very functional system.>
  I want to increase nitrates because I just bought 2 Crocea Clams from Clams Direct and read they and corals need some nitrates.
<It is true that these animals do benefit from some dissolved organics in the water column. T. Crocea in my experience is the most light demanding of clams and while it too appreciates "food" it derives most of it's energy from the zooxanthellae within it's mantle.  Having said that I wouldn't mess with your system to much, it sounds like it's well balanced and functional. What I might recommend is the addition of phytoplankton, look into reactors if you have the time, effort...as phyto is best fed on a continual drip. If you can't go the reactor route I would at least power the skimmer down or off for an hour or so after feeding the clams.>
Please suggest some ways to safely increase.
Thanks, Joel
<Adam J.>

Question... Very interesting observations of the effects of adding an Archaster/Sifting Star   3/29/07
Hi Crew!
<Rowan>
Hello, hoping you can help me.  I haven't seen specifically this answer in your archives, so maybe it's a new one.
<Many "to go">
We recently added a Sand-Sifting Starfish to our 120 Gallon tank.  Our testing levels were all within parameters (ammonia=0, nitrites=0, nitrates=0, PH=8.1, etc) just prior to adding "him", but almost immediately (within a hour or two) we noticed something funny was going on in the tank as the soft corals started to emit some "waste/chemicals" starting with the coral on the one side of the tank and working it's way towards the right.
<Ah...>
  Almost reminding me of a "wave" at a baseball game if you can imagine.  Our fish seemed more "irritated" than usual (i.e. the tank "bully" our zebrasoma was bullying without any cause to ALL inhabitants,
<Good observations>
which is not normally the case also normally rather peaceful fish like our Blue/Green Chromis' nipped at some larger species of fish (like our Tomato Clown) which is again, highly unusual).  So, since it was such a drastic change, checked water parameters again only to find the nitrates soared from a reading of zero, to a reading of 60 or more ppm!
<Mmmm>
So, obviously a water change was in order.  This morning, I tested for all parameters again: ammonia-0; nitrite=0; and nitrate=80+.  Remembering what I had read thru one of your threads, it had been suggested in such a scenario to check the water source (RO/DI water) before the tank to be sure that the test kit was still "good".  The source water is a zero for nitrates.  So, noticing again that I will need to change some more water out when I get home from work, I bring you to my question.
Is it possible that the reason for such a drastic spike was caused by the only new addition to our tank, a sand-sifting starfish which we acquired to help stir up the aragonite bed?
<Yes, possible... Probable>
Vacuuming has never seemed to help very much with the amount of detritus at the bottom of our gravel, there is always more!  Is the detritus on the bottom being stirred into the environment creating a nitrate haven that even my skimmer cannot keep up with?  
<Also a probable source>
Plus, once I've gotten the parameters in check again, should the system "settle in" again?
<Hopefully yes>
I do have a well fed aquarium, but as we've never encountered this problem before, and have no Cyano or other visibly "bad" algae and our fish do seem to gobble it all food offered down, although we've always noticed a brown colouration to our aragonite gravel bed under our purple coralline layer.
<Not to worry re this... actually beneficial>
Any help is much appreciated!  Love your site which is more valuable than any collection of books/advise from LFS,
Heather Allan
<Thank you for your kind words... and valuable, careful observations... I do think the Star was involved directly in chemically stirring the cnidarians in your system... by its chemical presence as well as the stirring of the substrate. And I suspect all will re-settle here in short order. Bob Fenner>

Nitrates and Canister Filters
Hello, 
<Hello David>
I have a 55 gallon tank with 75 lbs of live rock, and approximately 3 inches of live sand (no plenum). I am using an Aqua-c remora with a Maxi-jet 1200 for protein skimming, and have another Maxi-jet 1200 for circulation. In addition, I have been running a FilStar Canister filter (300gph). The canister filter, however, only contains foam filter pads. 
Marine life in the tank consists of two Clarkii clowns, a yellow tang, bi-color blenny, six line wrasse, and some assorted snails and crabs for house-cleaning. Nitrates in the tank tend to hover around 20-30, despite 20% water changes every two weeks. I am also very conscious about not over-feeding.
Is it possible that the canister filter is contributing to higher than normal nitrate levels? Would a larger protein skimmer bring the levels down, or is this just the reality of keeping a relatively small reef-tank? Much of the reading I have done suggest that under-tank refugiums can be very beneficial in reducing nitrates. However, I want to make sure there is not something in my current set-up causing abnormally high nitrates, before investing all that additional money. Any thoughts or suggestions would be much appreciated. 
<The use of canister filters requires religious cleaning of the foam pads weekly. The detritus it traps leads to higher nitrates levels if these pads are not cleaned weekly. The waste is still in the water, just in a different place. I would suggest the use of Chemi-Pure in the filter for improved water quality. I've been using this in a canister filter for quite sometime, and changing pads weekly. My nitrates are barely detectable and I don't have as efficient of a skimmer as you. Give it a try. James (Salty Dog)>

Bio-Bale question
Hey guys. Love reading your stuff. Quick question, Does CPR's Bio-Bale hold nitrates like the bio-balls do? Thanks in advance.
<Am pretty sure this stuff is just polyethylene (turnings, like from a drill bit working a solid piece)... Will definitely encourage the forward reactions of nitrification... but not "hold" nitrates... more likely to experience more/higher concentration with its use than not... I have mainly removed this material from CPR's products... Bob Fenner> 

Canister filter inserts and Nitrate 5/16/05
Greetings WWM Denizens! Thank you for all the advice, info and time spent accumulating it! You have gotten me from freshwater to saltwater, which may explain my configuration and question/problem. (I've searched the forums and can't find my particular query.) My problem is nitrates (surprise, surprise), and I wanted to know if my solution would work . <Thanks for the kind words! Glad you have benefited from the info here.>
Tank is converted from freshwater, about 9 months old with salt as follows: 100 gallons, Aqua C Remora Pro, with the larger skimmer, about 50 pounds of live rock--adding more slowly; 40 pounds of lava rock, which I am hoping will slowly become live rock (it has only been in saltwater tank); 3 powerheads knocking water around; my good old Fluval 403 from the previous century; an Eheim 2217; I also have about an inch of crushed coral for cushioning and prettiness. 
<Sounds reasonable, although adding live rock slowly is often a problem since each new piece has to cycle. I strongly suggest setting up a small tank (even a plastic tub) to cycle new rock in before adding to the tank. Also, lava rock can be unpredictable in composition and is a risk for introducing contaminants (especially metals). I would personally lean toward removing this in favor of live rock.>
The problem is nitrates. No matter how careful I am with feeding and how much goop my skimmer picks up, the nitrates will not drop below 15-20. (Ammonia always 0, pH 7.8 to 8.0, treating with 1 Tsp washing soda each 25 gallon water change.) I use RO water from a nearby ice and water store (about $60/year at 25 gallon change every four weeks), which I test for nitrates every now and then, so that's not the source. 
Forgot livestock--one perc, two yellow medium sized tangs, one dwarf coral beauty--that's all! 
<Your stocking is reasonable, but your pH is a bit low. I would urge you to check alkalinity (especially if you are adding washing soda). You nitrates are likely a result of two things... since your ammonia and nitrate are being processed in the highly aerobic canister filters, nitrate is being produced away from the live rock. 
When the nitrate is produced on/in the live rock, it can be further reduced to nitrogen gas in the anaerobic zones in the rock. You probably have enough rock now to completely take over biological filtration. In any case, such a small amount of nitrate is probably not a problem.>
The long term plan/solution is to add a sump/refugium, but until I can figure out how to explain that to my wife, I'm stuck with the canisters. 
<The sump/refugium will have many benefits, but in the mean time, keep those canisters squeaky clean! A good rinsing of the media in a small amount of tank water weekly will help a lot. Also, I have found that many expenditures can be (mostly truthfully ;^)) be rationalized to your spouse by explaining that it will save money in lost livestock.>
From reading the posts, I think I understand you all agree that weekly--yikes!--changes/cleaning of the foam/pads would help with reducing nitrates. Although I spend time every day with my beloved tank, opening those things once a week (or every other week) isn't going to happen. (See previous comment about wife and add "traipsing water across the living room" and you'll understand why.) 
<If you aren't going to maintain them, I would get rid of them or gut the media from them and use them only for water movement. Even when perfectly maintained, they aren't providing you with much benefit and you could sell them for money for more live rock.>
So here's my thought: How about just using no foam, poly filters, or pads in the canisters and only leaving the Eheim pre-packaged materials, plastic pot scrubbers, and other "hard" porous materials that I have in there other than foam? Would that reduce the nitrates without losing all the benefits of the filters? (If so, I would like to do half plastic
pot scrubbers on top and half the rock-type stuff that is in there now, if that would work.) Then, would 2-3 month cleanings of the rock-stuff/pot scrubbers be adequate? I'm keeping my fingers crossed. Other than the nitrates, everything in the tank seems to be quite happy (including some very full Xenia and a couple of mushrooms). Thank you again for your assistance. Greg 
<The nitrates are a result of both the accumulated organic matter and the highly aerobic nature of these filters. The media supplied with these (and plastic "pot scrubbers" make great high surface area, aerobic media. I would maintain them properly or gut them completely of all media.>
PS I would like to chime in that Sally Lightfoot crabs, in my opinion, ARE killers. I lost a bunch of damsels and a cardinalfish to one before figuring out what was going on. 
PPS Since this is my first question posted, I have to say again, you guys are great! 
<I couldn't agree more! In my opinion there are no completely safe crabs (including hermits). Best Regards. AdamC.>

Bioballs vs. Live Rock - 07/13/05
Dear All;
<<Greetings>>
Thanks for the great site! It has been a truly valuable source for me.  I am new to marine aquaria, but I have had fresh water systems for many many years.  It has been somewhat difficult making the transition, if not for your site it would have been an even more daunting task.
<<"Thanks" from the crew...gratifying to know.>>
I have been reading on WWM about the use of bioballs in a reef tank.  The general opinion seems to be that they should be avoided and the use of just live rock/sand bed in a refugium should be implemented.
<<Agreed>>
However, I have not read a sound, convincing argument about why bioballs act as "nitrate factory" and live rock does not.
<<Really?>>
Could someone offer a concise self-contained sound argument.
<<Not asking for much, eh? <G> >>
If a system has both live rock and bioballs then how does having the bioballs convert ammonia eventually to nitrates differ from the live rock doing the work?
<<Ok let's see...concise...hmm...  The process is essentially the same for converting ammonia to nitrite to nitrate whether it's done by the bioballs or the live rock, as you have already surmised.  The difference comes after the conversion of nitrite to nitrate... The pore structure of the live rock (or the grain-size/depth of a sand bed) creates anoxic zones; not commonly associated with bioballs, that foster bacteria which can/will process nitrates converting them to nitrogen, which is then liberated from the tank as the bubbles you see rising from the rock/sand bed.  The bioball/wet-dry filters are referred to as nitrate factories because their end product is just that...nitrate...and they are so efficient at it even when used in conjunction with live rock they can overwhelm the live rock's ability to convert same to nitrogen.  Thus, most prefer to exclude bioballs from reef systems...though they can be quite handy for dealing with large/fluctuating bioloads in FO/FOWLR systems that can handle a higher nitrate load.>>
Your time is sincerely appreciated.
-Kenny
<<Regards, Eric R.>>

High nitrates with a wet-dry? Of course! - 8/13/05  
Hi there,  
<Howdy, Ali here>
  I have enjoyed your website and reading through all the advice. I've told everybody even the LFS. But despite all the reading I wanted to see if  you can help me with my situation.
<Sure>
I have: 29gal. mini reef 30"x12"x18", approx. 52 lbs. Live rock, 30lbs.  live sand,  Coralife PC one 65watt 10,000K daylight and one 65watt  actinic, ProClear Aquatic System 125 wet/dry with 266 Bioballs in Biotower, CA  2200 return pump at 685gph, Aqualine motorized protein skimmer in sump. Two  Lifetech powerheads 295gph each on timer one for 6hrs in one direction then the  other in
opposite direction for 6hrs and so on.
<I'd keep your powerheads on simultaneously and take them off of the wavemaker device.>
Adding Kent marine's Essential Elements, Tech-I, and Purple-up according to directions on each bottle.
<All are unnecessary. A good two-part calcium/alk. supplement would be all you truely need. Bi-ionic or C-Balance, do a search on these.>
temp. avg 78,  LFS tested water parameters and all was where it  should be except for NITRATES >200ppm said one LFS. So I was told to do a  water change and I did a 30% water change. Next day LFS tested water and  this time Nitrates where at about 40ppm. Did another 30% water change and I  tested my water for nitrates and still high>40ppm. I was also told to siphon  the sand which I
did before the water change. LFS said that it could be the  Bioball sand advised to take some out but you guys have said to remove them  all out slowly and replace with LR.
<Unfortunately my friend, you have been receiving bad advice from your LFS. This is not uncommon so please don't feel singled out.>
Livestock: 1 Pair of (not mated) Gold Stripe maroon clownfish one  is 1.5" the other approx 3",
<Not a good choice for this size tank. A healthy pair of clownfish do make for a really pretty, calming yet humorous display. Unfortunately, the maroons not only get big - but very aggressive. Look into a pair of A. percula, A. ocellaris or some neat skunks.>
1 diamond watch goby, 2 Brown colored BTA purchased together because both were and still are occupying the same rock so I bought the rock and the Anemones. Clowns have gone into anemone and enjoy it. 1 blood shrimp. I have read the articles and seen the FAQs but concerned for my tank crashing with the high nitrates.
<Unless you enjoy doing daily water changes, remove the wet-dry system ASAP. Look into doing a tank renovation, with a 3" fine grade aragonite sandbed layer (CaribSea Aragamax Select works perfect for this, and given your tank dimensions 1 x 30 pound bag should get the job done.) Read here: http://wetwebmedia.com/reef2.htm  >  
I have read about turning the wet/dry to a sump Refu. but not sure how to do it with the DSB and the pump in there as well as where to place the live rocks with this kind of "generic" or  "standard" wet/dry? And how do I position the light for the LR and the  DSB in the wet/dry because at the top of the Bio tower is where the water  from the tank comes in?
<With a little creativity, you can make all this work Felix. If that is not possible, consider removing the entire wet-dry filter unit and purchasing a standard Berlin style sump or utilizing an empty aquarium.>
If I make a DSB in the sump would I still need to siphon  that sand as well?
<No need to do this Felix>
Also the bottom of the wet/dry has white spots or fuzz  along the walls.
<These are harmless critters. Don't worry about them. :) >
Sorry about the length but I wanted to make sure I gave as much information as possible. Please let me know what my next course of action should be. If left  any missing info please let me know so I may provide it for you.
Thank you so much for your time and keep up the good work
thank you
Felix
<Good luck and make sure you read the provided links Felix, all of the set-up, filtration, sandbed, answers you are looking for are thoroughly explained. - Ali>

BioWheel removal... nitrates 9/1/05
Thank you so much for all your help. One of your comments spurred a new question. You said "Sounds okay for this particular system. Removing the "bio-wheel" will help with nitrate issues a bit"  Do you mean removing the Bio-wheel system or just the rotating paper wheels?  How will that help with the nitrates?  
<Hi again Judson! Remove the bio-wheel, do a search on the nitrification process. The bio-wheel/wet-dry has no way of 'eating-up' nitrates. It converts ammonia/nitrites to nitrates which will continue to build up. Focus on using your liverock, sand, skimmer and water circulation as your main source of keeping your water clean. - Ali>

Not so mysterious nitrate mystery - 11/12/2005
Hello,
<Hello.>
I have nitrate problems! They are always 60ppm or more.
<Whew...for a minute there I thought you said...oh wait...YIKES!> 
If I do a water change the nitrates go down for a day?
<Are these large (extremely) water changes? If you're properly aging/storing the water, you'd be safe to do another the next day.>
This is my tank:
50gal saltwater
2 Fluval 304's (with bio-max, ChemiPure and nitrate sponge)
<Hopefully cleaned regularly.>
1 SeaClone protein skimmer
1 402 powerhead
crushed coral
<At what size/depth? Could be part of the problem. Do you vacuum this with the water changes?>
NO under gravel filter
NO live rocks
NO live sand
<Both are quite helpful. Do research them here.>
<<Um.. yeah, where do the nitrifying bacteria get to live?  MH>>
14" inch snowflake moray eel
2" humu trigger
Just 2 fish?
<Just two messy, high waste producing fish.>
However I just took 2 porcupine puffers out of the tank 1 week ago they both were 5 inches long" then I did a 50% water change. Still have the problem.
<Good grief man. This is a horrible stocking plan (for lack of a better word). 
<<Oh, please do emphasize this.  No WONDER you've got such a problem!  MH>>
Do take a read through the FAQs on this eel. Your skimmer is inadequate and your tank is undersized. I'm surprised you haven't had more problems than just water quality. - Josh>

High Nitrates from Feeding/Overstocking
Hello Guys,
Hope you're all well. As you can tell I have nitrate problems and it being such a common headache for newcomers like myself, I searched your archives for answers. Found some answers but I still can't figure out the exact cause & remedy so I'm asking you guys...I've a 40g FOWLR (3 mushrooms came with one of the rocks). I've over 100lbs of LR which I've added gradually over the past 3 months since I first set up the tank. Below are the order in which I've added livestock at 2 wk intervals since the set up:
14" Zebra Moray & 3" Spiny Burrfish
Medium sized Cleaner Shrimp & one turbo snail
Small Camelback Shrimp
Small Red Hermit
3" Maroon Clown
All are doing very well. Ammonia and nitrites have always been zero.  pH consistently at 8.5. Salinity consistently at 1.025. Nitrates started out ok averaging 40ppm. In the past 3 weeks, It has spiked to as high as 100ppm. I've been doing 33% water changes fortnightly. Since the spike, I've increased it to weekly (aging the water for 2 days) but the nitrates are still around 100ppm. I don't feed the invertebrates at all. They do a pretty good clean up. I feed the clown flake food daily. I feed the Spiny Burrfish daily with 2pcs of small krill. I started feeding the Zebra 3" of frozen crab leg every 4 days (first 4 weeks) but lately he seems to be always hungry (chasing after the Burrfish's krill) So I started feeding it daily. Changed his diet to frozen shrimp (2" worth every feeding). This is when I noticed the spike in nitrates.  So I'm guessing the spike is from overfeeding or from the juices of the frozen foods? If so, how often should I feed them? Btw, my LR generates lots of debris which I vacuum away with every water change. Could this be a cause as well? Or am I overstocked? 
<Desmond, you are very much overstocked. Your moray alone is too much for this tank. These fish are large waste producers. Your going to have to find a home for the moray, or get him a bigger home.>
What can I do to reduce the nitrates? 
<You need to eliminate the moray. Until then, you will be fighting a battle you can't win.> 
I can't afford to do water changes everyday! Salt mixes are expensive! As is a denitrifying coil! 
<I don't like the coils and this is just a band aid. The only way to be successful in nitrate control is to control nutrients. Your system is way out of balance.> 
And I've no more space for more LR!
<You stated you have over 100 lbs of live rock. How much actual water capacity do you think you have in that 40? Desmond, I'll post a link here. Scroll down this link and there is some info here on stocking levels. You will be surprised.  http://www.wetwebmedia.com/stocking1.htm >

Nitrates
Hello,
I have a nitrate problem... please help. I have a 50 gal salt water tank
-70 lbs of crushed coral
-undergravel filter with 2 402 powerheads
-a SeaClone 100 skimmer
-1 Fluval 304 with just sponges and bio-max
-1 Fluval 304 with sponges, charcoal, Bio-Max and Kent nitrate sponge.
Fish: 
2 porcupine puffers 4-5 inches long
1 humu trigger
1 snowflake moray eel
Nitrates are 80-100 ppm
What is your advice?   
Thank you,
Tony 
<Two things, Tony. First, you have too big a fish load for a 50 gallon tank. Just the two puffers at 4-5 inches would be pushing it, let alone the trigger and the eel. Secondly, the undergravel filter isn't helping you. The gravel bed on the filter plate needs to be gravel vacuumed weekly along with a 10% weekly water change that should be done. The addition of a protein skimmer will help immensely toward lowering nitrate levels. James (Salty Dog)>

Nitrates Follow-up
Hello,
Is it best that I take the under gravel filter plate out? I will be moving in 2 or 3 months so I will have to break the tank down anyway. 
<I'd take it out>
Also what are my options if I want to keep the 4 fish that I have in the 50 gallon tank (fish: 2 porcupine puffers 4-5 inches long, 1 Humu trigger 2 inches long, 1 snowflake moray eel 12 inches long)? If I had to would I be okay with just taking the Humu trigger out?
<Nope> 
How big will the puffers get? 
<This puffer can grow to 18 inches, the trigger to 10 inches. My rule of thumb is one cubic inch of fish per 5 gallons tank size. You will always have a nitrate problem with that big of a load in a 50. James (Salty Dog)> 

Reefs tanks and trickle filters 5/2/04
I hope you folks can clear something up for me.  I often see postings to the effect that trickle filters are bad for reef tanks because they produce nitrate.
<in some ways this is true>
This doesn't make any sense to me.  It seems to me that the bio-filtration of a trickle filter does not create any nutrients, it only changes their form.  
<correct... but unlike live rock and live sand which can complete the process with denitrification, trickle filters can only nitrify... and produce lingering nitrate>
Any nitrate it produces would otherwise have been ammonia or nitrite, which I believe to be more toxic than nitrate.  
<not correct my friend... some organics are used/assimilated directly by reef invertebrates and do not even enter nitrification by filters. But when such filters are employed, they are in direct competition with those inverts and filter feeders. The option here is utilization by the animals... or nitrification by the trickle filter: hence the "nitrate producing" argument>
So it seems to me that while a trickle filter may not be necessary for a reef tank, one should not be concerned about it's nitrate production. Am I right?
<nope... but thanks for asking :) Do read more about this popular topic in our wetwebmedia.com archives. Anthony>

Nitrate Issues
I have an eighty gallon tank I have two dog face puffers and a grouper. <Wow, you ought to be out tank-shopping> I cant get my nitrate level down I've tried everything. <Yes, you're dangerously over the limits here with bio-load.> Frequent water changes, feeding them less. <Skimming should be increased, and the grouper should be removed.> My tank has been established for about two years and I've never had this problem with the nitrate level please help. <They grow, eat more, produce more waste.> Also my dog face scratches himself along the bottom of my tank he also looks discolored a lot. <Lots of possibilities here: http://www.wetwebmedia.com/parasiti.htm> I've treated him with copper treatment and it doesn't seem to help. <Puffers, and other scale-less should be treated with a copper alternative.>  He's been less active as well.  <Yes, I'd find at least one of these fish a new home, or start exporting more nutrients from your system.>
Any help or suggestions would be appreciated.
<Good luck, Ryan>
Nathan

Is my BioWheel creating more nitrates?
    I have a 46 gallon tank that has been up about 3 months.  I have a Emperor 400 and a Bak Pak 2r.  I also have about 50 pounds of live rock and two weeks ago I increased my sand bed to 4". Last night I noticed my nitrates had gone up to 20 ppm and this is after doing a 5 gal. change the day before (and every week since the tank cycled). I don't think I am over stocked with two Percula clowns (1") and a bi-color blenny (1-2") for fish and a cleaner shrimp 6 Nassarius snails and 2 Turbo's. I also have a colt coral, green star polyps, some button polyps (5 came on live rock have since increased to 13) and a red open brain (in the substrate). do you think the bio wheels in the Emperor should be removed or should I leave them. << I would leave them.  I like BioWheels. >> could
this be part of the nitrate jump or is it the sand working itself in. << I would suggest more live rock, and more sand.  Also if you do water changes, don't disturb your sand bed.  Give it time to settle and create the bacteria areas you need.  Try feeding less to your fish, like feed them once per week. >>
thanks Jeremy
<<  Blundell  >>

Plagued with Nitrates
<hello! Ryan with you today>
I have a 55 gallon fish only marine tank.  I have a Clown Trigger and a Sohal Tang in it. <Hmmm...have you made future plans to expand?  That Sohal alone is going to require at least twice the volume that you're currently running.> I'm currently having a big problem with my nitrate levels. <Not exactly shocked> Which are at 80ppm.  I don't know how to lower it I've bought more live rock and I've used R/O water that I got from my local fish store.  The water here in my city straight out of the tap has anywhere between 40-80ppm of nitrate in it already. <What did the local fishkeepers do to deserve that?> That's why I've been buying the R/O water. <Very smart> I just changed 10 gallons of water using R/O water and my levels are still the same. <Yes, you need to keep fish that are well suited for your setup.  You're trying to do too much.> I don't have the money to buy the nitrate reductor. <And, you'd likely have just as many problems.> Will a better protein skimmer work? <Yes, it will help prevent the nitrates from rising, but it certainly won't solve the problem.  The one I have isn't all that.  Any suggestions would be great cause I really don't know what do about this problem.  
<Well, it's back to the drawing board, my friend.  You've got 2 "gross polluters," and something has got to give.  Please either seriously consider upgrading, or take these two magnificent specimens back to the LFS that shouldn't have sold them to you in the first place.  If you're set on keeping one of the two, the clown trigger will do better in the short term, but eventually also will need a bigger home.  Sorry to be the bearer of bad news!  Ryan> Thank you
for your time
                                         Scott

-Rising nitrate levels...-
let me just say have just found your site and it is very helpful GREAT SITE tank has been running for 6 months with no problems until now no3 gone up to 25mg/l  no2 is 0 running 2 Eheim filters 1 thermo prof 2 with Ehfisubstrat & Ehfimech <If these are bio and/or mechanical filters, this is likely the root of your nitrate accumulation> and the other 1 model 2222 pro with just active carbon and running threw a UV  2 power heads red sea protein skimmer 25 kilos of live rock I use ro for water changes have been doing water changes weekly last 3 weeks since it went up <Oh, only up for 3 weeks? If the rock was cured in the tank, and just finished curing, a nitrate level of 25 would be expected.> do you think I am using the right media in thermo filter. <You really don't need/want anything in the filters besides a periodic stash of carbon.> new to marines so any advice would be great, regards john <I hope this helps, also check out http://www.wetwebmedia.com/no3probfaqsii.htm and the four (count em!) other nitrate FAQ's, you're not the only one! -Kevin>

- High Nitrates, Small Tank -
Bob,
<Another crew member, JasonC here...>
Hope you can help me with a few questions. <I can try.> I have a 26 gallon saltwater tank with 10lbs of live rock, 40 lbs of AragAlive fine sand (1-1/4") a 60 gallon trickle filter with bio-balls (Purigen under bio balls). The tank is stocked with very small blue tang, clown, bi-color pseudo, cleaner shrimp, flame scallop, rose anemone, a few snails and crabs, bubble coral, green star polyps, metallic green moon brain coral. I am also running a 75 gallon protein skimmer. I am doing 20% water changes every two weeks. All parameters test perfect with the exception of Nitrates. My Nitrates are consistently between 20-30. Is this a deadly level for fish? <No, marine fish can usually take up to 50-ish ppm before they start to show the effect.> What about corals? <High nitrates are no good for corals and other invertebrates.> My brain coral has lost most of its color and has produced cobwebs that stretch out to my LR. I am quite certain it is dead or almost there. Blue tang and pseudo are battling ich. The cleaner shrimp is helping them through this. <I wouldn't rely on the cleaner shrimp - they can take care of day to day issues, but rarely can get on top of an genuine outbreak.> Tried dosing the tank with kick-ich twice but not much luck. <Wouldn't dose anything in your display - much better to remove the fish and treat elsewhere.> The cleaner shrimp alone seems to do as much if not more than the kick-ich did without the shrimp?? Any recommendations on an effective reef safe ich med? <That's an oxymoron - there is no such thing. Reef-safe ich medications are usually not safe or not effective - one or the other.> I am feeding my fish and inverts every other day. I am also adding Cyclop-eeze for the corals. Fish like too. Rose and shrimp are hand fed frozen food like fish. I think my high nitrate problem is a combination of issues. 1) Overfeeding <Always a possibility.>
2) Small tank  3) Bio Balls <Unless these are completely submerged, a very likely source.> 4) Not changing blue/white filter pad often <Another likely suspect - these should be cleaned/replaced very frequently - perhaps every time you change the water.> 5) Not cleaning foam block in sump often (how often should I clean these two filter media's?) <Same as the foam pad - at least once a week.> I am cleaning the pre-filter sponge every two weeks. I do have an issue with spot algae. I have to clean it weekly but believe this is due to high lighting I am using (8 hours of 165 watts - 5watts per gallon) plus blind filtered sunlight that comes in through blinds all day. It is enough light for star polyp to be half open. I don't want to spend much more money on my system then I already have so plan on adding a poly filter at bottom of egg crate and using denitrate chips below that along with current Purigen. The only other thing I can think of doing that wouldn't add to much additional expense is adding one of those mini CPR in tank refugiums. The one that suctions on the inside, putting some live sand and Caulerpa inside. What do you think? Any other recommendations? <Address those other issues first - then see where you stand. Perhaps speed up the water changes, perhaps 5% a week.>
Thanks, Rob
<Cheers, J -- >

High Nitrates
Hey guys!
<Hello!>
I'm having a nitrate build up in my 215g reef system....its been up since early may, and has been going along great, but in the last 30 days or so, the nitrate has been rising from around 10ppm to about 40ppm now...all of the inhabitants seem fine, but this seems like a scary trend...
<Agreed>
I've been doing regular 35g h2o changes every 2 weeks....skimming aggressively....don't think I'm overfeeding....about 300lbs live rock....plenty of snails and crabs, no2 is near 0 ammonia near 0....
<You need zero for both of these. Has something died in the system recently?>
Ideas? btw, Anthony or Steven, did you guys ever receive that article about sexual reproduction of e. quads ???
<Not enough information. We need to know more about your filtration. Off-the-cuff, I would say something has died in the system or you're feeding too much>
Happy holidays !
<Happy holidays to you and yours!>

Nitrate Problem
Thanks for the reply.  As far as the live rock goes we are running 60lbs of live rock in the tank.  We do change filter media every 3-4 weeks depending. As to the stocking level there is not a great amount of fish in the tank mostly of them are smaller and we do have a decent cleanup crew with many crabs. I have a 72 gallon Salt tank setup for over 18 months now and during that time have had an incredible problem with nitrate levels in the tank.  I am currently using 2 Emperor 400 filters and a Fluval 280 on the tank as well as a red sea skimmer for protein.
<Bodda boom bodda bing! I think we may have found the source of the nitrates. Are you replacing the filter material in these canisters regularly? If you're slack with the maintenance of the filtration equipment that you mentioned, you will definitely have nitrates>
During the time that we have had the tank we have always had a problem getting nitrates under control: at best we did have the nitrates down to 5ppm but then again the nitrates spiked to over 150ppm.
<That is excessive. This could also be a sign of overstocking. Is the stocking rate of the tank realistic?>
We have tried everything from water changes every 3-5 weeks to at this point I am running nearly a lb of Denitrate in the various filters.
<I feel reasonably sure the problem is the old filter media. Change the media regularly (weekly) but don't remove all the media in all the filters at once. Have a rotating schedule...do water changes weekly, and analyze your stocking level. This should take care of it. Oh...I also see no mention of live rock>
This does seem to be helping as now the nitrates are starting to fall but I was curious as to any other suggestions that you may have.  Thank you.
<My friend, you are correct. As you seem to realize what good does it do to treat the symptom without finding the cause? Check out wetwebmedia.com for more information. David Dowless>

- Defining the Nitrate Factory -
<Greetings, JasonC here...>
Thanks for the great web site. It is the most useful and informative site that I have found on  any subject, period. Coming from fresh water I am having trouble understanding the Nitrate factory view of filters. <You know what? So am I... I personally think it's something that is being blown out of proportion.> I am just getting ready to set up a 90gl .FOWsomeLR and will add more LR later. It seems to me that a high flow/oxygenated media would remove Ammonia and Nitrites quicker then live rock, but would do nothing for Nitrates. How can a filter be too effective at getting the first two out since they are so toxic to fish? <Well, any biological filter doesn't really 'get rid' of those nitrogenous wastes, it just breaks them down into less-harmful compounds; nitrate is the end product.> A wet/dry couldn't actually make more Nitrate from the same biological input than LR (could it?) <It could... wet/dry filters are highly efficient and would be able to process more waste sooner.> If was just using a DSB and LR for anaerobic processing of Nitrates how does a wet/dry impede this ability? <It doesn't, the nitrate would still be resident in the system, and the DSB and live rock would help keep the levels low.> Much thanks for any Help.
Jeff Mahan
<Cheers, J -- >

Reduced Nitrates
indeed, coming from somewhere, I sent bob an email yesterday in regards to tossing the rest of my bio-balls in my W/D, was running 20ppm nitrates yesterday,18 hours after removing the balls, I've tested 0-5ppm nitrates, that's great and another thing off my list in this battle, the Naso tang and lion are likely going tomorrow, cutting down on fish load should help, I will get a yellow tang to see if he helps, thanks for your help here Jason, and tell Bob thanks for assuring me about the balls,
<You're welcome>
very happy to see trace levels of nitrate now, btw, if I'm running such low nitrates now, does this mean i can/should cut back on water changes?, was doing 20g a week but this is because of the nitrates, now am wondering if this much is needed......riot...
<Frequent, partial water changes are a good idea... but twice a month is fine for these. Bob Fenner>

Media Replacement And Skimmer Choices (Pt. 2)
Thanx again!  Now changing the foam media on a weekly matter will in itself help keep down the Nitrate levels in the tank would it not?
<Yep! That's the best reason to do this! It's a viable "nutrient export" mechanism, as you're literally removing undesirable substances directly from the system. If you are a serious fish nerd, like me- you'll get a few of these foam media inserts and rotate 'em out several times a week...Scary- but really an easy way to keep nasty stuff from ever accumulating to begin with!>
Also have you heard of the Back pack skimmer (doing a search right now on them but your opinions also appreciated)?  They seem to be sold in abundance at one of my local shops.
<Yep- The CPR Bak Pak is a great hang-on-the-tank skimmer, IMO. Productive, simple to clean, and reliable. Another fine choice is the Aqua C Remora Pro. In my opinion, you can't go wrong with either of these models, if serviced regularly! Good luck! ScottF>

Re: nitrates
Hello,
I am writing today with a question about lowering nitrates.
I have read many of your articles and FAQ, and I'm confused. Let me tell you about my set-up. I have a 55gal. , (2) emperor 280 filters, (1) hot magnum filter, and a Prizm skimmer. I have about 2 and a half inches of crushed coral and about 25 - 30 pounds of live rock.
<Here's the problem. A deep course bed of crushed coral traps detritus and wastes contributing to nitrate production. Also the biomedia in the filters produce nitrates. These need to be cleaned very regularly (weekly to biweekly) and simply not enough live rock for bio-capacity and for your mandarins, which need at least 75 lbs of well established live rock per fish to survive. This is completely inadequate for these fish. Please read about Mandarins at WetWebMedia.com.>
My inhabitants are 2 percula clownfish, 1 pair of mandarin Dragonettes, 1 pair of green spotted Dragonettes, 1 scooter blenny, 1 Sailfin tang, 1 long horned cowfish, 1 pair of seahorses, and some xenia coral. I also have 1 coral banded shrimp, and 2 camelback shrimp.
<An unusual mix. You are mixing fish from completely different environments, current needs, etc. Seahorses generally have specialized needs compared to high current fish like Sailfin Tangs, which incidentally get to be 16", WAY too big for a 55.>
I change 10 gallons every other week. I cannot seem to lower my nitrates, I have tried chemicals (prime - works for a short time) so I thought the problem was in my tap water, so I bought a tap water filter for changes. Now my question; I have been reading a lot about DSB, should I replace my coral with sand?
<Very disruptive and stressful to your current inhabitants. Some of these fish are hard to keep, esp. in such circumstances. I would change substrates, but this would require a great deal of effort regarding established/establishing the needed food supply for mandarins, etc. Real serious vacuuming would be a good start, too much crud in substrate.  Not enough live rock to provide bio-capacity/denitrification.>
I am trying to understand Plenum Systems, should I put sand on top of my coral with a screen in between.
<Definitely not!!! a bigger waste trap. Do you see, wastes are the problem, and nitrate is the end game unless you have the live rock and sand to process it naturally.>
Or maybe I should just increase my live rock.
<Deal with substrate and more rock definitely!  A larger tank would be the ideal for the Tang and Mandarins. Please read about Sailfin Tangs (and any other fish) at WetWebMedia.com.>
Nitrates are my only problem, I have no ammonia or nitrite. Also I feed my fish live brine shrimp and frozen Mysis everyday.
,I would use the brine to get them eating if difficult to feed, then wean to Mysis only. Brine shrimp are the Hostess Twinkie of fish food. Pretty much junk food.>
This is my first marine tank, and I am looking for a cure not just a quick fix.
<You have a nitrate factory in your substrate and filter media, take care of those and increase bio-capacity with LR and perhaps LS with proper precautions. (be wary of releasing toxic wastes by disturbing dirty substrate without vacuuming wastes in doing so).
Also, larger water changes with above maintenance will help, maybe 10% per week according to water tests to get to desired levels.>
Any suggestions will be greatly appreciated. Thank you for taking your time to read this letter.  Sincerely, Linda
<Our pleasure Linda, hope this gets you on track! Craig>

NITRATES !!!!!! AHHHHHHHHHH !!!
Hi WWM crew …
<Howdy, Don with you tonight>
I have a 40 gallon FO Marine tank with 5 damsels, one snowflake eel that jumped out for the first time and seems, so far, alive after putting it back, and 1 tomato clown. The fish have been thru a lot, I mean a lot, with Ick and PH fluctuations and temp. fluctuations but now all is good and dandy. I have everything under control now with the PH, the sickness and the temp. thanks to u. BUT I have one problem. My nitrates, all along, are shooting thru the roof. I mean, I can’t seem to get them down for nothing. My Ammonia is 0. My nitrites are 0 also. And my Nitrates are around 60ppm !!! I have an Eheim Ecco canister filter, crushed coral as my substrate and a Berlin skimmer (that I had just bought 2 days ago). The reason why I have the skimmer is because I have read on WWM that it would essentially get rid of the Nitrates or at least decrease the amount. The liquid I’m getting is light beige color, out of my skimmer. Is that true? and what else do u think I should do to get this Nitrate situation under control? And when and if I do get this under control, could u provide me with a link that I could read up on how to convert my FO tank to a reef/coral with fishes.
<The skimmer will help. Beige? Maybe the color of tea? Sounds OK. Looking for dark color and good daily output. Try to cut down on the amount of food and perform 10% water changes for a few days. The canister filter needs to be kept very clean (like daily). The crushed coral can trap a lot of detritus so you want to keep it clean as well. For more reef info, check here: http://www.wetwebmedia.com/reef1.htm.>
Thanks Guys. I really am bad with hobbies and I usually lose total interest in hobbies that are complicated and boring. But honestly, the subjects on WWM and help that u guys give us hobbyists is unbelievably awesome and has helped me thru a lot with this hobby and keeping me interested and I’m sure with all the support u guys give, I will most definitely stay in the hobby for a long long long time.
<Glad to help, Don>
Regards,
Ash

Nitrates won't come down
Hi!
<cheers>
You have been very helpful in the past and I come to you with another query.
I am having a problem with nitrates staying close to 100 ppm in my 75 gal marine tank. The tank has been set up since early May. It has a 3" sandbed and 150 lbs of Florida live rock. 
<wow! Young tank... DSB and heavy live rock! Its unusual to have high nitrates in light of all of this. My first intuitive guess is that the sand grain is not fine (sugar/oolitic grade) or that it is mixed/coarse. Coarse sand grades are poor at denitrification and mist very very thick compared to sugar fine grades to work comparably. Over 5" thick needed here and very strong water flow in the tank is a must. Also, I wonder if you have been getting dark skimmate every day from your skimmer... a common flaw to not have a tweaked skimmer>
I have a sump with an AquaC EV120 skimmer.
No other filtration. 
<no worries... plenty of rock and sand>
The sump does have a coarse filter sponge in the baffle between the skimmer and the Mag 7 return pump. I clean the sponge about once a week to get rid of the detritus it catches. 
<outstanding and little addition to nitrates here>
I have recently also added a mesh bag with activated carbon. I am running two Maxijet 1200 powerheads in the tank for additional circulation. 
<good move to keep detritus in suspension for skimmer>
I have been changing 10 gal of water once a week (sometimes twice) in the last month and a half. This is about 15% of the actual water volume. 
<perhaps larger water changes needed to keep pace>
I use RO water from a drinking water machine at the local supermarket for all my water changes and top-offs. Using tap water results in fairly bad diatom blooms so I've never used any on this tank, not even for the initial fill. I just ordered an RO/DI unit which I expect to get next week.
Nitrates had gone over 100 ppm (kit only shows 100 and 200 ppm) but the water changes are keeping them somewhere between 50 and 100 ppm according to my Salifert and Red Sea test kits. Nitrites are also between 0.1 and 0.2 ppm. 
<that almost sounds like a misreading?!? I cannot fathom nitrites existing in this tank. Do confirm on another brand of test kit>
Ammonia is 0. Ca is 450 ppm and Alk is 3.2 meq/l. pH is 8.3. I don't know why I can't keep nitrates (and nitrites) closer to 0. I think the tank has been up long enough for the nitrites to have gone down to 0.
<agreed>
A picture of my tank can be found at
http://wetwebfotos.com/Home?actionRequest=userview&userID=819 but the tree
sponges and gorgonians in that picture are now gone. I took them out after some comments from Anthony.
the tank is stocked as follows:
Fish:
1 Blue Damsel
2 Percula clowns
1 Royal Gramma
1 medium Purple Tang
1 Blue (Hippo) Tang - this is the largest fish at 3.5 to 4"
< a fine selection of fishes and no significant source of nitrate here... at least nothing out of the ordinary. Still doubting test kits>
Invertebrates:
1 cleaner shrimp
2 peppermint shrimp
1 coral banded shrimp
1 cup coral
1 frogspawn
1 hammerhead coral
1 brown zoanthid colony (turns white when the polyps retract)
Misc mushrooms and polyps snails and miscellaneous life that came with the live rock and live sand from the Florida coast of the Gulf of Mexico. There are probably a dozen mollusks attached to the live rock, all live.
<very cool>
I've had the damsel, clowns and coral banded shrimp for about three years.
They started out in a 10 gal tank.
I feed the tank one cube of either Formula One or Formula Two thawed in tank water every two days and I also add a narrow strip of Nori a couple of times a week. Sometimes I feed a cube of frozen Mysis instead of the Formula x. 
<all light feeding>
I add DT's phytoplankton (about 15 ml, three capfuls) twice a week for the filter feeders. Could this regimen be the cause of my nitrate problem?
<hmmm... perhaps a source indeed... take a capful in a sample of aquarium water and tees after some days... just for a ballpark idea on what a concentrated solution can do>
Would it be OK for the fish to cut back further on the feeding? 
<your feeding of fish and corals already seems light... cutting back should not be necessary>
The food seems to be consumed very quickly. I wouldn't mind removing the hippo tang, since he's the dirtiest of the fish, but there's no way I can catch him without taking out a lot of the liverock and causing a major disturbance in the tank.
<actually... the waste of these fishes is what in part will keep many of your corals alive unless they get target fed. The problem again is not your feeding amounts (modest). I'm wondering about skimmer performance or test kit accuracy>
The livestock seems to be doing well but I am concerned about the coral's long term health since I read here nitrates should be kept at a minimum and certainly a lot less than 50-100 ppm. Based on what I've read it seems I should have a big algae problem, but I don't. There's some red algae that builds up under the sand level between the sand and the glass, but it is pretty light and there is nothing above the sand level. Running a stick between the sand and the glass gets rid of it immediately. 
<very fine>
I don't have any angel hair algae but the back panel of the tank is covered with small deep green dots and coralline algae that I want to let grow over the rear glass surface.
Am I making too much out of the nitrate level I have? 
<somewhat yes>
I may start doing larger water changes, 
<excellent>
but I really would prefer to find the source of my problem and fix it there.
<agreed... as per above suggestions>
Thanks for any insights or suggestions you might have.
Henry
<best regards, Anthony>

Re: Nitrates won't come down
Anthony: Thanks for the information. I don't trust the nitrite test either because the Salifert kit had them down at 0 before and the colors it produces are
not the easiest to interpret, although it is clearly not 0. They don't quite match anything on the color chart. Unfortunately I no longer have the Salifert kit. I will get another one. The two nitrate tests I have (Salifert and Red Sea) do agree with each other so I think the nitrate readings are accurate.
<interesting>
Your guess about the sand is a good one. The sand is not particularly coarse but it is not oolithic either. It is straight sand from the Gulf of Mexico, similar what you find on the beach in Cancun or elsewhere in the Caribbean.
Making it thicker in the main tank would be difficult because of all the live rock.
<ahhh...understood>
Would it help to add a 3 or 4" oolithic sandbed in the sump? 
<yes... perhaps a refugium or sump with more than 4" of sugar fine sand will do the trick (denitrification) where coarse sand cannot. Unlit is fine with a good strong flow over it>
If so, would it need special seeding or will enough life make its way to the sump from the main tank? 
<just a handful of live sand to inoculate it would be enough>
The sump area is dark. Lighting it might be an option but most of the sump area is taken up by the skimmer and pumps. 
<no need... easier unlit here>
I would also need to figure out some way to keep the skimmer pump submerged. There's a baffle right before the main pump and water is perhaps 8" deep.
<all sump skimmers need a well or reservoir of their own (even a bucket with an overflow to drain in to the sump). It is critical; that a skimmer receives all raw overflowing water but it cannot be at the mercy of a fluctuating sump level (evaporation, etc) or skimmer performance will be compromised>
The skimmer does foam all the time but it takes 2-3 days to reach the overflow outlet of the cup. I will adjust it to see if I can get more foam production. 
<if the skimmer is sitting in the open sump, that may be a large part of the problem...see here: http://www.wetwebmedia.com/plumbingmarart.htm >
I find I need to clean the pre-filter on the Mag 5 often to avoid pump performance from degrading.
<the frequent cleanings are helpful but their need indicates a flaw in the system that allows such detritus to accumulate. Such matter should be kept in suspension for the skimmer to export. This does bring us back to water flow and skimmer performance needing tweaked>
Is 50-100 ppm nitrate acceptable for the LPS and other invertebrates I listed? 
<somewhat stressful but not fatal to many>
I don't want to make too much out of these readings if my livestock is fine. I initially wrote because I thought I needed readings under 20 ppm.
<indeed under 20ppm is recommended>
Thanks again for your wonderful site and the help you provide.
Henry
<our great pleasure... thanks kindly. Anthony>

Re: Nitrates won't come down
You are quick on the replies!
<yes :) Here at WetWebMedia.com you have one of the rare exceptions of getting more than you pay for <G>>
I am still confused about the cleaning of the pre-filters of the skimmer pump. 
<no worries... I shall try to illuminate>
The pump is right next to where the water comes from the tank into the sump. Anthony says:
"the frequent cleanings are helpful but their need indicates a flaw in the system that allows such detritus to accumulate. Such matter should be kept in suspension for the skimmer to export. This does bring us back to water flow and skimmer performance needing tweaked".
Since the pump is where the raw water comes in, that chamber contains detritus from the tank. That detritus gets trapped at the foam block on the intake of the skimmer pump (what I am calling pre-filter). 
<yes! That is exactly the problem! Unless that foam block is cleaned daily in an attempt to prevent the biological nitrification of trapped waste... you have a filter that is generating Nitrates that could otherwise export said nutrients (raw water to the skimmer) BEFORE they have a chance to break down into nitrates>
The pre-filter is meant to avoid any big items from entering the pump. 
<that is the flaw, my friend... you want all raw organics...particulate and dissolved to enter skimmer with hopes of ending up in the skimmer cup BEFORE turning into nitrate in the system>
Of course there's buildup there because the skimmer hasn't skimmed that water. Why wouldn't you expect this foam block to get this accumulation? Are you saying I should remove the pre-filter so the pump can push all the detritus into the skimmer? 
<exactly... it is a common filter design flaw>
I was just afraid something could make its way down from the overflow box in the tank and cause a problem in the skimmer pump, however, I now see where the pre-filter might be doing more harm than good. 
<bingo, bub>
There's also a foam block on the baffle before the return pump trapping this detritus, but some still makes its way to the other chamber, where it gets trapped by the pre-filter on the Mag 7 return pump.
<this last stage polishing foam block isn't as bad as long as you clean it weekly or more often and it doesn't accumulate much. More often, I forgo it>
Henry
<best regards, Anthony>

Wet Dry Nitrate Factories?
Hello Bob,
I need some education regarding wetdry filters being nitrate factories but first the setup...
140 gal FOWLR with wetdry filter
Aquaclear skimmer
~100 LBS live rock
Inhabitants are an Emperor angel, Maroon Clown, Pacific Blue Tang, Convict Tang, Sailfin Tang, Scissortail Goby, Lawnmower Blenny, 2 neon gobies, plus some number of red tip hermits and turbo snails. This tank has been running for about a year. For maintenance I do a 20 gallon water change every 2 - 3 weeks and change the filter fiber, clean the skimmer etc. while doing the water change. My nitrate levels have always remained well below 10 ppm (I use the FasTest kit which has a lowest reading of 10ppm.)
<Good maintenance, live rock... careful feeding...>
>From what I have read from various sources, I should be pulling out my bio balls because the huge amounts of aerobic nitrifying bacteria growing on bio balls should be cranking out nitrate like crazy given the load on this tank.
I'm struggling with this concept since it has always been my belief that the number of bacteria present is dependent on how much ammonia/nitrite is being produced.
<One principal factor... as is a relative availability of aerobic, hypoxic, anaerobic space... detritus, circulation, types of foods...>
If this is the case how would a wet dry system produce more nitrate than other types of filtration?
<"Driving" the "forward" reaction of nitrification over its reciprocal complement (denitrification)... you may well have a relatively uncommon situation of "good" mix of livestock, feeding, upkeep, live rock, substrate... If you're satisfied with the under 10 ppm. nitrate readings in such a FOWLR system (I would be), then I wouldn't change much>
Is it really just a maintenance issue of detritus collecting on the bioballs over time? 
<These possibly, and other major to minor inputs>
If you could either explain to me or point me to any information (books, articles, etc.) explaining how a wetdry filter can produce more nitrate than other filter systems I would greatly appreciate it?
<... perhaps better to encourage you to do experiments... increasing the feeding, trying more frequent water changes... The energetics of the reaction series that yield more/less nitrate accumulation are straightforward... if there is more source material (ammonia, nitrite), less aerobic activity and/or more anaerobic digestion... the equation/balance of accumulated metabolites will/does shift from higher/lower. Do you want specific reference as in articles on biological filtration? What books, magazines do you have access to? I will take a look at what matches in our references. Bob Fenner>
Thanks in advance,
Richard

Nitrate Reduction
Dear WWM crew,
<Scott F. with you today>
First off, I'd like to put out my thanks for all of your time and effort spent helping fellow hobbyists.
Now, for the crisis. I have a 29 gallon FOWLR tank with a 5 gallon refugium containing Caulerpa prolifera and a nice large number of visible pods, a 10 gallon sump with a trickle tower containing DLS, and a diy skimmer (counter current). The trickle tower and skimmer were just added in the last few days to replace the two penguin bio wheels that are running on the tank. The substrate in the tank is only enough to cover the bottom as I had always read that deep sand beds were a negative thing in marine aquaria. Really regret that I didn't know about your site at the setup point, but I do plan on adding a good 3 inches of sand to the tank and the sump.
<Good idea on the sand bed-deeper than 3 inches would-be even better.>
The inhabitants are a pair of ocellaris clowns and a coral beauty angel, as well as a peppermint shrimp and a myriad of creatures that come out of the live rock when the lights are off:)
Here's the problem- we just recently lost a very healthy (seemingly) Sailfin tang that we had for about 3 weeks or so. We found him lying upside down or on his side of the bottom of the tank gasping. The other fish were just fine. Every water parameter checked out accept the nitrates, which were in the 100 ppm range. <Yikes!>
We've done a six gallon water change, and then another roughly one week later, but the nitrate remains the same. Thick clumps of emerald green algae appeared in different spots in the tank, but have now died back and been replaced with brown algae.
Worrying profusely about her precious clown fish, my significant other has convinced me to do a massive water change to reduce the nitrates, as the smaller ones did nothing, and fearing her clowns will be lost to nitrate poisoning.
At present, the water is mixing, but I fear that a large change (75% or so) will cause to great a shock to the fish and actually be their demise. <Better to perform smaller, regular changes>
Also, the peppermint shrimp, a rock crab (in the refugium), and a tiny brittle star are all still alive and well- but I would assume that the nitrate level would do them in far before the tang?
I sincerely appreciate you time,
Thank you,
Daniel
<Your high nitrate level and algae bloom are indicative of a high nutrient level. There are somethings you can do to reduce this-adding a deeper sand bed, as outlined above, institute regular water changes, siphoning detritus as you go. You really should not use DLS material, or for that matter, bioballs, in your filters, as the DLS is a detritus trap, and the bioballs are essentially working against your deep sand bed by producing nitrate. Make sure your skimmer is adjusted to produce at least a cup of dark, yucky stuff weekly. And finally, if you really want to use Caulerpa in your sump, do harvest it regularly-a good source of nutrient export. Be careful not to rip the fronds while doing this. Keep reading on the wetwebmedia site for more information on maintenance. Good luck!- Scott F>

Nitrate and Clownfish
Hello again! I hope this finds you all well.
<Scott F. back with you again>
I spent the day researching again, and decided on some "field work" to boot. I searched one of the LFS's that we like to use on occasion for more opinions (on your ideas) and for some comparison for my poor clown. I'm afraid I made a poor impression, but all is well that ends well, right? I told him of your suggestion for removing the bioballs upon addition (or a week or so after) of the DSB.....this had him pondering back and forth and finally he decided that he agreed with you, though he could not understand why it could not be a two inch sand bed, which I just had to let go, as I could not explain it to his satisfaction.
That taken care of, I spotted several tanks of tank raised tomatoes and ocellaris that had some of the same markings on their white patches, which is what ours looked like at the start; I asked him what he could make of it, and I honestly believe that he had no idea, taking my "bait" with the marks having to do with the high nitrate levels....he was adamant that my clown's situation is indeed due to the high nitrates. I read every piece of Brooklynella information on WWM pages, and concluded that he is showing none of the symptoms for it. Still a mystery to me, any ideas besides Brooklynella? Daniel thinks that it could be Hole-in-the-head/HLLD...what do you think?
<It's a distant possibility- this malady generally causes markings and/or pits in the skin due to skin loss; usually found near the no surprise here-head or lateral line area on the fish. It is rarely fatal, it just looks bad. All kinds of "remedies" exist for this malady, ranging from the addition of vitamins in the fishes' foods, to daily water changes, to grounding the tank from stray voltage, etc. This might even be "normal" coloration for this strain of captive-bred clowns?>
I am very concerned even though he is still eating well, and behaving as usual.
<Just keep a close eye on these fish and follow good maintenance practices. Be prepared to act decisively should the need arise> 
The nitrates as of this afternoon are just under 20ppm by the way.)
<definitely a positive trend. Good job!>
I also asked him about the Caulerpa (which is all they sell) and if/when they might have other plant life available for us.....I'm afraid he thinks I'm crazy now, and we will more than likely not be using this store for any further saltwater related items.
<Well, now you've crossed over that threshold into the realm of "fish nerd"-just like me, and there is no known no cure for that! :)>
Our next research will be in the refugium section of WWM for better options. What *would* we do without you guys?!
<Buy lots of Caulerpa, maybe? LOL>
Thanks again immensely for your time, opinions and educated guesses.
Kelly and Daniel
in Houston
<You're welcome. Feel free to contact us any time!>

Nitrate Crisis (Part 2)
WWM Crew:
<Scott F. with you again>
(Kelly here, Daniel sent you guys the first note; I am the "significant other" worrying profusely *grin*.)
Thank you so much (everyone) for how quickly you are able to answer our e-mails, and how dedicated to education you all are. I need to make some clarifications, and your response has sparked a few different questions. I think the best way will be to cut in on the existing dialog with my own input and shoot for some clarity to this "muddy" situation! He works nights, so communication is not always optimal.... Sorry for the length, by the way.
>*He has removed the DLS at my insistence, prior to the water changes today, Chemipure and poly filter and carbon are all in place as well.*
<Good!>
*The nitrates at this go round (finding my beloved Sailfin) were nearing 40ppm, and we did not test again after the second 6 gallon water change until last night (see below)...I'm afraid he was mistaken about the 100ppm, it was very high, but in truth the test from last night was between 60 and 80, he read the test more than an hour after I took the sample and tested it which was last night....there is more on this below, it's very hard to clarify. Daniel may have been trying to condense our experience for the sake of your time which we both greatly appreciate.*
<That's what I'm here for, it's okay>
*Do you think we might find a balance in raising the sandbed to 4 inches in both the tank and the refugium, keeping the bioballs in the filter? Daniel also suggested partitioning the sump to add a nice deep sandbed there as well. The reason for this question is oxygen, as the tanks day to day temperature here in Houston in the summer is determined by how much A/C we can afford! He has essentially built the entire system: wet/dry, skimmer, refugium, sump, and hood (awaiting better lighting), and I'm sure he can modify it to your suggestions.*
<I think that increasing the sand depth and retaining the bioballs would be kind of counter-productive, sort of a "tug-of-war" with no winner>
>Make sure your skimmer is adjusted to produce at least a cup of 
>dark, yucky stuff weekly. And finally, if you really want to use 
>Caulerpa in your sump,
*I'm sorry to be a pain, but I've read through some of the Caulerpa FAQ's and found nothing on how to actually "harvest" it. Essentially harvesting the Caulerpa would be in fact "ripping the fronds" no? I thought it was the runner that you are to keep from damaging. Maybe I missed something...? We are both confused by your reply.*
<Sorry for the confusion! It's almost impossible not to rip some of the fronds when harvesting Caulerpa, but you can gently pull lengths of it out in clumps. You just don't want to radically rip it out, because there are numerous toxic compounds that can be released into the water which are not too good for the life in your tank. In the long run, I'd eliminate Caulerpa. just ask Anthony- he loves to tell people that "Friends don't let friends by Caulerpa!"
>do harvest it regularly-a good source of nutrient export. Be careful not to rip the fronds while doing this. Keep reading on the wetwebmedia site for more information on maintenance.>
*Thank you again for all your time and effort, the website itself is such a plethora of information that I'm sure I miss some things every time I'm there! I hope I was able to clarify our situation for you.
Take care :)
Kelly (and Daniel)
in Houston
<Glad I could help-let us know if you have any more questions- Regards, Scott F.>

Toxic Water (Nitrates)
Hi, I am having a problem with my tank. Last month my nitrates were 200 and my nitrites were 10.
<Ugh!>
I don't understand how because I did a 20% water change monthly.
<Well, lets work this through. Let us assume your tank produces 1 ppm nitrate per month. Now, you do a water change of 20% each month and lets also assume (which is not always true) that the new water you use has zero nitrates. The 1 ppm you had at the end of the first month is now (after the water change) 0.8 ppm. Now after the second month, you have 1.8 ppm nitrates, which you do a water change and bring it down to 1.44 ppm. Month three, it increased to 2.44 and was brought down to 1.95 ppm. Do you get the progression? Nitrates accumulate and need to be monitored monthly, so you can later your husbandry.>
My tank is 55 gallons and my filtration includes a wet-dry good up to 150 gallons and a Prizm skimmer good up to 75 gallons.
<Your Prizm needs to be accumulating a cup of dark skimmate everyday.>
I also have a UV sterilizer 200 watt. I did a 50% water change and that didn't not bring the levels down.
<It should have cut the levels in half. Perhaps your test kit is inaccurate or not sensitive enough to distinguish between 100 and 200 ppm. Both are too high. The other possibility is to check your new saltwater. It may not be free from nitrates, either from the raw water you are using or from your salt mix.>
I put a nitrate sponge in my sump as well as activated carbon.
<IME, these have little to no impact.>
I also put a Polyfilter in my drip pan. I cut back on feeding to once every other day too. The levels after one week were nitrates 200 and nitrites 0.5 ppm.
<Well, at least the nitrites have gone down.>
I noticed my dogface puffer has been getting ich off and on for the past month since these levels were elevated, tonight he is covered with it. My levels from yesterday were salinity 1.021, temp 80, nitrates 200, nitrites 0.5 ppm. What can I do to get them down?
<A series of 50% water changes using nitrate free water.>
I did a 10% water change yesterday.
<This will do next to nothing.>
Should I do these daily or weekly?
<I would perform a 50% water change every other day until your nitrates have dropped to 20 ppm.>
What percentage should I be doing?
<See above>
Please help. Thank you. JPK
<Good luck! -Steven Pro>

Does eliminating bio balls help eliminate nitrate
Dear Bob,
<Gage here this evening.>
I had the opportunity pleasure to meet you many years ago, (about 5 years) back in Monroeville PA. This is where I lived and worked in the trade for about 5 years before returning to my native home of California. I moved from Pittsburgh to Rancho Santa (South Orange County) back in 99 where I still live today.
I have a question with regards to the true "Berlin" system. If I am correct, the true Berlin system is a bare bottom tank with good circulation, live rock, sump and a good proteins skimmer and micron prefilters.
The main goal is to eliminate the need for any outside biological filtering media such as bio balls, with the purpose of eliminating a breading ground for Nitrosomonas and Nitrobacter bacteria, which then eliminates the nitrogen cycle and it's final waste product of Nitrate. Does this make since......if not bare with me.
Nitrobacter bacteria grow on any and all surface areas that are provided with oxygenated water, and they only colonies in amounts that are needed based on the waist load. So, if you have a sump with bio balls, how could this contribute to the nitrate problem; If the bio balls are available, the bacteria will colonies on them, and it will also grow on other surface areas in the aquarium (liverock, glass walls, etc).
If the bio balls are removed, since the Nitrobacter bacteria only grows to the amount needed, the same amount of bacteria would then just colonies in other areas of the aquarium system, still producing the same amount of nitrate, which is then removed by skimming and water changes.
So my question is: Does eliminating bio balls really help reduce nitrate?
<Sort of. If you remove the bio balls you will need to replace them with something else, like more live rock. Pound for pound the live rock is much better at filtering your water and removing nitrates.>
or am I completely wrong in my theory because the skimmer is suppose to remove all waste before the nitrogen cycle has a chance to happen?
<The nitrogen cycle is going to happen no matter what. Using live rock in your filter instead of bio balls will ensure that you are better equipped to handle the nitrogen cycle. Check out the link below for some good info http://wetwebmedia.com/nitratesmar.htm>
Thanks for your time with regards to this matter. Sincerely, Mike Proctor
P.S. Tell Anthony I said hello...he might remember me as "The Fish Guy", my aquarium service in Monroeville.
<will be sure to, best regards, Gage>

Location of articles specifically explaining benefit of removing biomedia from wet dry filter
Hello and thank you for reading this. 
<Hi Richard>
I have gone through most of your articles regarding the benefits of removing the bio media in a wet dry filter. My question is what specifically is the benefit of removing the bio media from the wet dry trickle filter. 
<These bio-media convert nitrite to nitrate as a dead-end process awaiting your export via water change. Removing them and relying instead on 1 -1.5 lbs of live rock per gallon and deep sand beds further breaks the nitrate down to it's gaseous form in the deep anoxic recesses in the rock and sand and it rises to the surface of the water. This does not preclude removing other non-nitrogenous wastes and replacing vital elements with regular water changes.> 
I understand from your articles that the live rock and live sand will do the job of the plates or bio balls or whatever was in the wet dry. But specifically what is the benefit. For example does live rock and live sand take the denitrification a step further, for example convert nitrates into some other substance?
<Yes, gaseous form, as above>
Does relying on the live rock and live sand remove the need for water changes? 
<No.>
I currently am using a wet dry trickle filter as well as live rock and live sand in a 90 gallon tank. The inhabitants include three damsels two perculas about 30- 40 pounds of mixed live rock and 3-4 inches of live aragonite sand. Things are going fine everything is thriving as long as I change around 20 gallons of water a month. Will removing the bio media in my wet dry trickle filter improve my water quality to the degree that water changes are no longer needed or are needed less frequently? If you would kindly point me in the right direction I would greatly appreciate the insight. Thanks. Richard Slocum
<I would advise adding more LR before removing the wet/dry although you have a relatively light bio-load. There is much more on live rock and sand on WetWebMedia.com. Scroll to the bottom of the page and type "live rock" into the google search engine. Craig> 

Source of Nitrates
Hi. I was wondering if my elevation in nitrates (200 ppm) can be the result of my 200 watt UV sterilizer on my 55 gallon aquarium?
<Nope>
Is the UV light killing off all the good bacteria to get rid of the nitrates?
<No, UV's only kill what is passed through them. Denitrifying bacteria only occur in low oxygen environments; deep sand beds and deep inside porous live rock. They would never be free floating and going through the UV. Nitrates accumulate from overfeeding, overstocking, poor nutrient export, not large enough or frequent enough water changes, from low grade salt mixes, from source water, etc. Please examine these possibilities and take corrective measures.>
Thanks, JPK
<You are welcome. -Steven Pro>

Nitrate Nightmare
Hi WWM Crew!
<Scott F. here today!>
I have a 55g FOWLR, 120g FOWLR and a 20g tank that is currently without fish but running. I have had constant problems with  high nitrates in all three of my tanks.  I recently changed from buying  water from my LFS to mixing and storing my own salt water. I store and  mix the water in a 30g trash can with 2 powerheads constantly running. I haven't yet, but I also intend to add a heater.  So far I have only been using the container for makeup water, so on my first run of using it for a water change, I mixed the salt and Amquel and let the water aerate for 2 days before doing a water change.  Immediately after doing a 20g water change to my 120g tank, I did a water test that indicated the nitrates were high in the tank.
<May be in part because of high nitrate present in source water, but also possibly due to husbandry. Do re-visit your maintenance procedures, feeding, skimming, etc., to make sure that these factors are not contributing to the problem. Fortunately, these are easy to correct!>
I have the Saltwater Master Liquid Test Kit that uses a color chart for readings, so it's very hard to tell exact numbers, but let's just say it read that the nitrates were fairly high. Anyway, after realizing that the nitrates were high in the tank, I tested the stored water.  I realize that I should've tested it before doing the water change, but I'm learning as I go.  : )
<Hey- at least you're testing! That's great. Don't be so hard on yourself!>
I found that the pH level was low, so next time I will buffer the water to bring it to 8.2.
<Good procedure>
I also  found that the nitrites were high
<Bingo!>
....this is where my query comes in.  My thinking on the issue is that by using Amquel to get rid of chlorine and ammonia, the ammonia is converting to nitrite during storage and then to nitrate in the tank.  Does this sound logical?
<A very interesting theory, but I'm inclined to believe that the fresh water was high in nitrate to begin with, and certainly not helping the existing nitrate situation in your tanks. When you're starting out with source water that's, say, 5ppm or more nitrate, you're "behind the eight ball" already!>
If so, what can I do to remedy the problem? If this explanation doesn't sound right, what do you suggest?
<I'd recommend that you invest in a good RO/DI unit that can produce virtually pure water at a modest cost. This way, at least you can be assured that you're starting with good source water>
Seeing that I have 3 tanks, it got to be quite cumbersome getting saltwater from the store, so I really want to learn to mix my own water.
<Agreed- been there- done that!>
Does this sound like a problem that a chemical tap water purifier could fix or is an RO/DI unit in order, or is there something else that I'm missing?
<Nope- as above- an RO/DI should help. But do investigate husbandry, maintenance, etc. to help reduce nitrate levels in your tanks.>
Thanks in advance for your help.  You guys are the coolest!
<Not as cool as our readers! Keep up your efforts at learning and improving your systems! You're doing great! Regards, Scott F.>

Rubbermaid got nitrate
Looking to set up a Rubbermaid 150 gal sump out of one of there stock tanks. Question is, do you know if Rubbermaid has nitrate in the plastic? Have heard that this might be a problem for a reef tank.  Thanks.
<Mmm, made of Polyethylene... carbon, hydrogen, oxygen... no nitrogen... no nitrate. No problem. Bob Fenner>

Dastardly Dascyllus Behavior
Steven,
You can disregard the question on the clown (Waddles). As of this morning, he is eating and swimming all over the tank. Hope his days of being stress-free are over.
<I am glad to hear it.>
As for my Domino, so far so good and I'm keeping my fingers crossed.
<You can hope, but this fish is going to be a fish. No changing its behavior. Domino's are categorically one of the meanest fish out there.>
I know he'll eventually have to go, as I wish to purchase some Cardinalfish in the future.
<Agreed>
As for my second question, I don't think you answered it.
<Perhaps I was not clear enough.>
My nitrates (been at this same level for 2-1/2 weeks or so) seem to be "stuck" at 25 mg/L (according to the test) and the guy at the LFS suggested I make a 20% water change since in his opinion, the tank seems to be "stuck" at the end of it's cycle.
<You LFS guy is incorrect about the cycle. You said you tank is run with an undergravel filter. If so, you will always have nitrates. You do not have a sand bed and are therefore unable to culture denitrifying bacteria. You will always have nitrates that you will have to continually try to dilute with water changes.>
Been up and running for 6 weeks, ammonia zero, salinity is normal. What is your advice on this? Should I make a water change?
<Yes, but do not think that eventually you will not have a need for them. Even with a DSB and complete denitrification there is always a need for water changes.>
Thanks, Maureen
<You are welcome. If I was not clear enough or you need further explanation, feel free to email again. -Steven Pro>

Unhappy new addition??
Hi there again, guys!
I have a zillion more questions for you, but I'll limit this session to just two. I have a 20 gallon saltwater, UGF, etc. I purchased a tank raised Percula clown yesterday, acclimated him, and he seemed okay. My yellow-tail blue damsel started attacking him and wouldn't leave him alone. He even tried to bite! He was smacking him in his face with it's tail and had him cornered and wouldn't let up.
<This is not unusual behavior for damsels. They are inherently territorial and aggressive.>
Needless to say that the damsel is now gone, but the clown (Waddles) is still hiding and won't eat. I had to really move around some rock to get that little @#*&@ out. Is he still unbelievable stressed or should he have a companion (there were 4 in his tank at the LFS)?
<I would bet on stress, damage, even just plain old fear.>
My Domino damsel doesn't bother him.
<No yet!>
Any suggestions?
<I always try to plan out every fish I put in a tank before I put any in. Come up with a game plan and you will have fewer problems like this in the future.>
Now on to question number 2. My tank has been up and running for over 6 weeks and my nitrates are still hovering around 25 ppm (according to how the test reads). The guy at the LFS suggested that I do a 20% water change since in his opinion it seems my tank is "stuck" (ammonia zero, salinity is normal). The nitrates have been at this level for about 2-1/2 weeks, maybe a little longer. Any suggestions on that as well?
<I am a bit confused. You will always have nitrates with an undergravel filter. You do not have a Deep Sand Bed to perform denitrification. Perhaps you should invest in Mike Paletta's "The New Marine Aquarium." It is an excellent first book. Very easy to read and pretty short, too.>
Thanks again, Maureen
<You are welcome. -Steven Pro>

Nitrate Problem
I have a 72 gallon Salt tank setup for over 18 months now and during that time have had an incredible problem with nitrate levels in the tank.  I am currently using 2 Emperor 400 filters and a Fluval 280 on the tank as well as a red sea skimmer for protein.
<Bodda boom bodda bing! I think we may have found the source of the nitrates. Are you replacing the filter material in these canisters regularly? If you're slack with the maintenance of the filtration equipment that you mentioned, you will definitely have nitrates>
During the time that we have had the tank we have always had a problem getting nitrates under control: at best we did have the nitrates down to 5ppm but then again the nitrates spiked to over 150ppm.
<That is excessive. This could also be a sign of overstocking. Is the stocking rate of the tank realistic?>
We have tried everything from water changes every 3-5 weeks to at this point I am running nearly a lb of Denitrate in the various filters.  
<I feel pretty sure the problem is the old filter media. Change the media regularly (weekly) but don't remove all the media in all the filters at once. Have a rotating schedule...do water changes weekly, and analyze your stocking level. This should take care of it. Oh...I also see no mention of live rock>
This does seem to be helping as now the nitrates are starting to fall but I was curious as to any other suggestions that you may have.  Thank you.
<My friend, you are correct. As you seem to realize what good does it do to treat the symptom without finding the cause? Check out wetwebmedia.com for more information. David Dowless>

Information overload...HELP!  11/12/2005
Thank-you for your help in advance. I've been a long time African Cichlid keeper starting out with a 10 gallon tank and working my way up to my existing 150 gallon bow front tank. I took time and patience in learning all I could through reading and the knowledge of others. Then, one fine day the salt water bug bite me. I'd like to convert my 150 gal in the future but right now I am using a 29 gallon starter tank to "get my hands wet" so to speak. 
Here is how things look so far: 40 lbs live sand, 40 lbs live rock, Red Sea Prizm protein skimmer that actually works (have read lots of not so good things), 1 rotating power head, Eheim Prof 2 2126 (with only filter pads and Chemi-pure) mostly for water movement and nitrate control and my lighting is 130w=12,000k, 420 actinic blue pc with 4 moonlight for lovely night time viewing. 
Specific Gravity 1.024, temp 81 deg, ph 8.4, ammonia 0ppm, nitrite 0ppm, calcium 410(use Kalkwasser drip once a week to replace 1gal of evaporation), GH/kH 8, but nitrate is always at 20ppm.
<"It's your filtration">
I do 10 percent water changes weekly as well as rinse/replace filter pads. Stock= 1 yellow tail damsel, 2 blue damsels, lawnmower blenny, sand sifting star, tiger striped star, fancy red star, multiple blue legged crags and a few snails. Not to mention all the beautiful life on the live rock. Now to my question -What am I doing wrong that my nitrates are so high?
<Mmm, nothing... due to your filtration mode, maintenance... See WWM re canister filters, maint...>
Any advice with my set-up?
<Mmm, not on this one, but I would read... maybe a few good marine aquarium books (biblio. on WWM), and our general marine aquarium set-up articles and FAQs files>
And with my current set-up would it be possible to have corals and the like?
<... some>
Worth noting- before using the Eheim I was using a Penguin 350 Bio-wheel filter but opted for more water movement. Thank you for your insight. Frankie
<I might put the Biowheel back on and run it at the same time. Bob Fenner> 

Trickle Filters as Nitrate Factories
I am a newbie and just found your site a couple of days ago. I can't leave it alone and can't tell you how much I've learned in a short period.
<Glad to hear it.>
Anyway I had a question that's been bugging me. I have read several places that trickle filters are nitrate factories. Wouldn't any biological filter stop generating nitrates as soon as the supply of ammonia and nitrites is depleted (which is what I want anyway)?
<Ammonia is produced constantly in our aquariums. The thing is when your tank is completely "cycled" the ammonia is converted/consumed nearly instantly into nitrate so that at any given time you get a zero reading from your ammonia test kit. Pretty much the same thing happens with nitrite, too. The main drawback to trickle filters is their incredible ability to nitrify many dissolved organics and turn them into nitrate too. You would much rather see your protein skimmer grab a hold of these compounds and export them from the system instead.>
Thanks, Darrell
<You are welcome. -Steven Pro>

High Phosphates and Nitrates
Hello,
I am posting this for a friend from my salt club, can you help?
<I'll try>
“I have been having some water chemistry problems lately that I can not figure out, so I am going to put it out there for you all to help with. About 2 months ago, I started getting high nitrate readings along with moderately high phos. Everything I have tried to get these down has failed or only worked for a short time, which equals failed in my book. I have nothing missing in the way of livestock, most of my corals are now doing fine, with the exception of the birds nest frag I got at the swap. I have tested the makeup water and it does not read any nitrate or phos. either. Tank readings this am are. pH. 8.0 (buffer added), Nitrite 0mg/L, Nitrate
>110 on one kit >120 on another, Phos. 1.0mg/L, Ammonia, 0 on both kits, KH 110, CA 300 (today is Kalk day).
<Elevating the pH with the Kalkwasser to about 8.5 (temporarily, it will drop soon on its own) will precipitate out most of the soluble phosphate here... But its source?...>
Tank is a 55 gal with 4-5in DSB, HOB BakPak skimmer, 4 Powerheads for circulation, Temp. remains at 78. Inhabitants: 2 tangs, 2 midas blennies, 1 blue damsel, 1 lawnmower, emerald and sally lightfoot crabs, 2 conch with multiple babies, 5 starfish of different varieties with multiple baby ones.
About 70lbs LR, Multiple corals of all varieties (SPS, LPS, Softies). Coralline growth is great. No nuisance algae. I have been struggling with red Cyano, but it appears to be controlled now.
<Here's a clue>
Photoperiod is 14hrs, first and last 2hrs are actinic only from 220w pc lighting. Any ideas? Suggestions?”
<It may well be that the measurable nitrate, phosphate are coming from the dissolving Cyanobacteria... or perhaps a mineral source in the system (substrate, rock...), overfeeding... Please have your friend read through this section of our root web: http://www.wetwebmedia.com/nitratesmar.htm and the linked FAQs files there. Bob Fenner>

High Phosphates and Nitrates
Hello,
I am posting this for a friend from my salt club, can you help?
<I will try.>
“I have been having some water chemistry problems lately that I cannot figure out, so I am going to put it out there for you all to help with. About 2 months ago, I started getting high nitrate readings along with moderately high phosphate. Everything I have tried to get these down has failed or only worked for a short time, which equals failed in my book.
<Agreed. This type of problem needs to be attacked at the root cause, not by attacking the symptoms.>
I have nothing missing in the way of livestock, most of my corals are now doing fine, with the exception of the birds nest frag I got at the swap.
<Phosphate is a known inhibitor of calcification.>
I have tested the makeup water and it does not read any nitrate or phosphate either.
<Is this some sort of purified water, RO or DI? Either one is preferable to tap water.>
Tank readings this am are pH 8.0 (buffer added), Nitrite 0 mg/L, Nitrate
>110 on one kit >120 on another,
<Indeed, quite high.>
Phosphate 1.0 mg/L,
<This will fuel nuisance algae, if not now, soon, particularly Cyanobacteria.>
Ammoni